期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 28, 期 6, 页码 2572-2583出版社
SPRINGER
DOI: 10.1007/s10904-018-0945-1
关键词
Copper oxide nanoparticles; Poly(o-anthranilic acid); Poly(o-aminophenol); Nanocomposite; Dielectric relation
Copper oxide nanoparticles (CuO-NPs) are prepared based on thermal decomposition method. Polyanthranilic acid (PANA) and poly-o-aminophenol (POAP) are synthesized based on the oxidative polymerization in aqueous medium with potassium dichromate. Thin films are fabricated from PANA/POAP blends and composites of PANA/POAP with 0.25 and 0.40wt% of CuO-NPs. The resulting thin films are characterized by different techniques such as XRD, SEM and UV-Vis absorption measurements. Surface morphology displays a good level of CuO-NPs distribution in POAP/PANA blends at 0.25wt%. Initial agglomeration detects at 0.4wt% concentration of CuO-NPs. It is found that the real dielectric constant (epsilon(real)) increases with increasing CuO-NPs content. Transmittance of PANA improves up to 95% in the presence of 50wt% POAP. I-V characteristics of the PANA/POAP blend and nanocomposite films show a non-ohmic behavior. The obtained results indicate that the poly(o-anthranilic acid)-poly(o-amino phenol)/copper oxide nanocomposites thin film is a good candidate in optoelectronic devices based on its band gap and dispersion parameters.
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