期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 22, 期 2, 页码 404-414出版社
SPRINGER
DOI: 10.1007/s10904-011-9569-4
关键词
Poly(2-hydroxyethyl methacrylate); KIT-6; Polymer-inorganic hybrid material; Palladium nanoparticle; Suzuki-Miyaura reaction
资金
- Islamic Azad University, Shahreza Branch (IAUSH) Research Council
- Center of Excellence in Chemistry
Pd nanoparticle-poly(2-hydroxyethyl methacrylate)/KIT-6 (Pd-PHEMA/KIT-6) composite was fabricated through in situ polymerization method and was evaluated as a novel heterogeneous catalyst in Suzuki-Miyaura cross coupling reactions of aryl halides and phenylboronic acid in an aqueous medium. The catalyst was characterized by XRD, FT-IR, UV-Vis, TG, BET, and TEM techniques. The results revealed that the supported catalyst Pd-PHEMA/KIT-6 exhibited excellent catalytic activity for the coupling of aryl iodides, aryl bromides, and aryl chlorides. This heterogeneous catalyst could be reused at least nine times without any decrease in activity.
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