期刊
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
卷 20, 期 4, 页码 2228-2235出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2013.09.055
关键词
Re catalyst; Heterogeneous catalysis; Alkanes; Oxygen; Selectivity
资金
- Foundation of Science and Technology (FCT), Portugal [PTDC/EQU-ERQ/110825/2009]
- Fundação para a Ciência e a Tecnologia [PTDC/EQU-ERQ/110825/2009] Funding Source: FCT
A series of tricarbonyl Re-(v) complexes, i.e. [Re(CO)(3)(K-3-PN2)] (1), [Re(CO)(3)Br(K-2-H2PNO)] (2), and [Re(CO)(3)Br(K-2-HPN-Pip)] (3), have been covalently anchored over modified SBA-15 as supported catalysts. Remarkably, high catalytic turnover numbers from 2240 to 2857 with high ketone selectivity was obtained for both C-5 and C-6-alkanes. Best oxidation condition was optimized by the variation of temperature, pressure, time and catalyst amount. A thermal stability test indicates that the catalysts are stable up to 200 degrees C and ICP shows negligible metal loss from the catalyst surface, after the 7th catalytic cycle, allowing further use. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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