Preparation, characterization and catalytic performance of HPW-TUD-1 catalyst on oxidative desulfurization

By incorporating H3PW12O40(HPW) heteropolyacid into mesoporous TUD-1 materials, a series of HPW-TUD-1 catalysts were synthesized. Nitrogen adsorption-desorption isotherm, XRD and FTIR characterizations showed that these catalyst exhibited mesoporous structure, and HPW presented in the catalysts with Keggin structure. The catalytic performances of the HPW-TUD-1 catalysts were tested through the oxidative desulfurization (ODS) process of dibenzothiophene (DBT) model oil. The results showed that the obtained 20HPW-TUD-1 catalyst displayed excellent catalytic activity and recover ability for ODS. The desulfurization rate of DBT reached up to 98.1%, and almost no catalytic activity loss was observed after three recycles of the catalyst. (c) 2012 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.