期刊
ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 19, 期 10, 页码 1356-1359出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.5b00148
关键词
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资金
- NIH NIGMS [R01GM100212]
In this manuscript we highlight the potential of stereospecific nickel-catalyzed cross-coupling reactions for applications in the pharmaceutical industry. Using an inexpensive and sustainable nickel catalyst, we report a gram-scale Kumada cross-coupling reaction. Reactions are highly stereospecific and proceed with inversion at the benzylic position. We also expand the scope of our reaction to incorporate isotopically labeled substituents.
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