期刊
ORGANIC LETTERS
卷 17, 期 14, 页码 3402-3405出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01223
关键词
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资金
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Ministry of Science and Technology of China [2012YQ120060]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
A highly selective radical dioxygenation of alkenes using hydroxamic acid and O-2 was developed, and copper/cobalt was used as the catalyst without assistance of any additional ligands or bases. Mechanistic investigation disclosed that copper salt and O-2 work in concert to activate hydroxamic acid, with Cu(I) and Cu(II) concurrently existing in this reaction.
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