期刊
ORGANIC LETTERS
卷 17, 期 7, 页码 1688-1691出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00456
关键词
-
资金
- National Natural Science Foundation of China [21372224, 21232008]
- Ministry of Science and Technology [2011CB808600]
- Chinese Academy of Sciences
An organocatalytic [3 + 2]-annulation between isatin-derived Morita-Baylis-Hillman adducts and cyclic sulfonimines has been developed in high yields with excellent enantio- and diastereoselectivities via an allylic nitrogen-ylide intermediate. The reaction provides access to heavily substituted aza-spirooxindole derivatives, which also contain ring fused cyclic sultams.
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