期刊
ORGANIC LETTERS
卷 17, 期 4, 页码 856-859出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5037024
关键词
-
资金
- U.S. Department of Health and Human Services (National Institute of General Medical Sciences) [GM-65597]
- Wayland E. Noland Fellowship
- University of Minnesota Graduate School Doctoral Dissertation Fellowship
We report here the efficient, intramolecular trapping in a Diels-Alder (DA) sense of thermally generated benzynes by one of two pendant arene rings. A more electron-rich ring (p-methoxyphenyl) reacted substantially faster than a simple phenyl ring, which was, in turn, slightly more reactive vs a 4-carbomethoxyphenyl ring. Photoinduced di-pi-methane rearrangement of the initial DA adducts gave rise to unusual isomeric polycyclic adducts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据