期刊
ORGANIC LETTERS
卷 17, 期 3, 页码 700-703出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5037198
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan [23108518, 25108719, 24710252]
- Nagase Science and Technology Foundation
- National Institutes of Health [R01 CA070375]
- Grants-in-Aid for Scientific Research [24710252, 25108719] Funding Source: KAKEN
Notoamide S has been hypothesized to be a key biosynthetic intermediate for characteristic metabolites stephacidin A, notoamide B, and versicolamide B in Aspergillus sp. but has not yet been isolated. The isolation of notoamide S and an enantiomeric mixture of 6-epi-stephacidin A enriched with the (-)-isomer from Aspergillus amoenus is reported. The presence of (+)-versicolamide B suggests that the fungus possesses only the oxidase, which converts (+)-6-epi-stephacidin A into (+)-Versicolamide B, but not for (-)-6-epi-Stephacidin A.
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