期刊
ORGANIC LETTERS
卷 17, 期 18, 页码 4404-4407出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01790
关键词
-
资金
- NIH [R01-GM100143, S10 RR08389, S10 RR024601]
- NSF [CHE-0342998, CHE-1048642]
Dehydrogenation of (partially) saturated heterocycles provides an important route to heteroaromatic compounds. A heterogeneous cobalt oxide catalyst, previously employed for aerobic oxidation of alcohols and amines, is shown to be effective for aerobic dehydrogenation of various 1,2,3,4-tetrahydroquinolines to the corresponding quinolines. The reactions proceed in good yields under mild conditions. Other N-heterocycles are also successfully oxidized to their aromatic counterparts.
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