期刊
ORGANIC LETTERS
卷 17, 期 6, 页码 1465-1468出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00348
关键词
-
资金
- DFG [KI 1289/1-3]
Two new gold(I)-catalyzed cascade reactions of 4-hydroxy- and 4-silyloxy-1,5-allenynes are disclosed, offering access to a variety of mono- and bicyclic, polyunsaturated carbonyl compounds. The diverse reactivity observed for the investigated allenyne system is controlled by the nature of the unsaturated substrate: Allenynes bearing a free hydroxyl group engage in what is likely an oxycyclization/allene-ene carbocyclization cascade, while their silylated analogues are converted through a carbocyclization/pinacol-type rearrangement process.
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