期刊
ORGANIC LETTERS
卷 17, 期 14, 页码 3624-3627出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01750
关键词
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资金
- NIGMS [R01 GM-081376]
- Eli Lilly
To develop a method for the synthesis of a class of azaborines, potassium 2-(trifluoroboratomethyl)-2,1-borazaronaphthalenes have been synthesized to serve as nucleophilic building blocks. In palladium-catalyzed cross-coupling reactions with (hetero)aryl chlorides they serve to produce a variety of pseudobenzylic (hetero)aryl substituted azaborines. Potassium 2-(trifluoroboratomethyl)-2,1-borazaronaphthalenes are crystalline solids that are more Stable than 2-(chloromethyl)-2,1-borazaronaphthalenes and have a broader substrate scope in cross-coupling reactions compared to their pseudobenzylic chloride counterparts.
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