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卷 17, 期 15, 页码 3786-3789出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01759
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Glycolates or glycinates derived from diversely substituted secondary cyclopropenylcarbinols have been involved for the first time in an Ireland-Claisen rearrangement. This reaction allows an efficient and stereoselective access to highly functionalized alkylidenecyclopropanes possessing an alpha-hydroxy or a-amino acid subunit, which in turn are valuable precursors of substituted cyclopropanes by diastereoselective hydrogenation of the exocyclic alkene.
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