期刊
ORGANIC LETTERS
卷 17, 期 8, 页码 1842-1845出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00401
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资金
- Wuhan University [203273463]
- Ministry of Education of China
- National Natural Science Foundation of China [21372179, 21432007, 21402145]
Rh/(R,S)-JosiPhos complex-catalyzed asymmetric hydrogenation of o-alkoxy tetrasubstituted enamides has been achieved, and it furnished a set of beta-amino alcohol analogues in high yields and excellent enantiomeric excesses (>99% conversion, up to 99% ee).This method provides valuable chiral building blocks in chiral pharmaceuticals and useful motifs for catalysts.
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