Application of iron electrode corrosion enhanced electrokinetic-Fenton oxidation to remediate diesel contaminated soils: A laboratory feasibility study

Diesel soil contamination on gas stations or refinery plants is a worldwide environmental problem. The main objectives of this study were to (1) evaluate the efficiency of electrokinetic (EK) by using different electrode materials (graphite and iron rods) and electrolytes (tap water, 0.01 M NaCl, and 0.1 M NaCl) on the remediation of diesel contaminated soils, and (2) evaluate the feasibility of total petroleum hydrocarbon-diesel (TPH-D) reducing in soils via EK-Fenton oxidation enhanced by corroded iron electrode. The EK and EK-Fenton experiments were conducted in batch and sand box experiments, respectively. Batch experiments reveal that the most appropriate electrolyte was 0.1 M NaCl when iron electrode was used in the EK system. Sand box experiments indicate that the TPH-D concentration dropped from 10,000 to 300 mg kg(-1) when amorphous iron/total iron (Fe-o/Fe-t) ratio increased from 0.1 to 0.33, with the addition of 8% of H2O2 and 0.1 M NaCl after 60 days of EK-Fenton operation. Electrokinetically enhanced oxidation with the presence of both H2O2 and Fe3O4 (iron electrode corrosion) resulted in higher TPH-D removal efficiency (97%) compared to the efficiencies observed from EK (55%) or Fenton oxidation (27%) alone. This demonstrates that EK-Fenton oxidation catalyzed by iron electrode corrosion is a valuable direction to efficiently and effectively remediate diesel contaminated soils. (C) 2009 Elsevier B.V. All rights reserved.