期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 33, 页码 8906-8911出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01125f
关键词
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资金
- 973 program [2011CB808600]
- NSFC [21222204, 21472049]
- Ministry of Education [NCET-11-0147]
- Ministry of Education (PCSIRT)
- Program of SSCS [13XD1401600]
We report an efficient Mukaiyama-aldol reaction of tryptanthrin with fluorinated enol silyl ethers, which is carried out in methanol without the use of any catalyst. This method is applied to the total synthesis of the difluoro analogues of the natural product Phaitanthrin B.
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