期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 360, 期 -, 页码 279-287出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2018.08.025
关键词
delta-Bi2O3; Surface oxygen vacancies; Selective adsorption; SeO(x)(2-)ions; Bonding mode
资金
- National Natural Science Foundation of China [51473081, 51672143]
- Outstanding Youth of Natural Science in Shandong Province [JQ201713]
- Taishan Scholars Program
- ARC [170103317]
- CSC (China Scholarship Council)
Removal of the toxic selenium compounds, selenite (SeO32-) and selenate (SeO42-), from contaminated water is imperative for environmental protection in both developing and industrialized countries. Providing high selectivity adsorbents to the target ions is a big challenge. Here we report that micro sphere-like delta-Bi2O3 (MS-delta-Bi2O3) with surface oxygen vacancy defects can capture hypertoxic SeOx2- anions from aqueous solutions with superior capacity and fast uptake rate. High capture selectivity to SeO32- anions is observed, since the O atoms of SeO32- anions fill the oxygen vacancies on the (111) facet of delta-Bi2O3 forming a stable complex structure. This mechanism is distinctly different from other known mechanisms for anion removal, and implies that we may utilize surface defects as highly efficient and selective sites to capture specific toxic species. Thus, we present a new route here to design superior adsorbents for toxic ions.
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