期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 239, 期 -, 页码 206-212出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2012.08.066
关键词
Dual cloud point extraction; Heavy metal ion; 8-Hydroxyquinoline; Pre-concentration and separation; Inductively coupled plasma optical emission spectrometry
资金
- Zhejiang Provincial Natural Science Foundation of China [202127]
A dual-cloud point extraction (d-CPE) procedure has been developed for simultaneous pre-concentration and separation of heavy metal ions (Cd2+, Co2+, Ni2+, Pb2+, Zn2+, and Cu2+ ion) in water samples by inductively coupled plasma optical emission spectrometry (ICP-OES). The procedure is based on forming complexes of metal ion with 8-hydroxyquinoline (8-HQ) into the as-formed Triton X-114 surfactant rich phase. Instead of direct injection or analysis, the surfactant rich phase containing the complexes was treated by nitric acid, and the detected ions were back extracted again into aqueous phase at the second cloud point extraction stage, and finally determined by ICP-OES. Under the optimum conditions (pH = 7.0, Triton X-114=0.05% (w/v), 8-HQ=2.0 x 10(-4) mol L-1, HNO3 = 0.8 mol L-1), the detection limits for Cd2+, Co2+, Ni2+, Pb2+, Zn2+, and Cu2+ ions were 0.01, 0.04, 0.01, 0.34, 0.05, and 0.04 mu g L-1, respectively. Relative standard deviation (RSD) values for 10 replicates at 100 mu g L-1 were lower than 6.0%. The proposed method could be successfully applied to the determination of Cd2+, Co2+, Ni2+, Pb2+, Zn2+, and Cu2+ ion in water samples. (C) 2012 Elsevier B.V. All rights reserved.
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