期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 219, 期 -, 页码 75-81出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2012.03.048
关键词
Energetics; Munitions; Degradation reduction; Bimetal; NTO; NQ; DNAN; RDX; HMX; TNT
A reductive technology based on a completely mixed two-phase reactor (bimetallic particles and aqueous stream) was developed for the treatment of aqueous effluents contaminated with nitramines and nitro-substituted energetic materials. Experimental degradation studies were performed using solutions of three high energetics (RDX, HMX, TNT) and three insensitive-munitions components (NTO, NQ, DNAN). The study shows that, on laboratory scale, these energetic compounds are easily degraded in solution by suspensions of bimetallic particles (Fe/Ni and Fe/Cu) prepared by electro-less deposition. The type of bimetal pair (Fe/Cu or Fe/Ni) does not appear to affect the degradation kinetics of RDX, HMX, and TNT. The degradation of all components followed apparent first-order kinetics. The half-lives of all compounds except NTO were under 10 min. Additional parameters affecting the degradation processes were solids loading and initial pH. (C) 2012 Elsevier B.V. All rights reserved.
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