4.7 Article

Stabilization/solidification of petroleum drill cuttings

期刊

JOURNAL OF HAZARDOUS MATERIALS
卷 174, 期 1-3, 页码 463-472

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ELSEVIER
DOI: 10.1016/j.jhazmat.2009.09.075

关键词

Petroleum drill cuttings; Stabilization/solidification (S/S); Cement; Fly ash; Factorial design; Waste utilization

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A systematic treatability study was conducted for the treatment of drill cuttings, a waste generated during petroleum exploration and production. by stabilization/solidification with Portland cement (CEM 1), with the addition of high carbon power plant fly ash (HCFA), an industrial by-product, as a novel sorbent for organic contaminants. A factorial design experiment was adopted to investigate the effects of waste-to-binder ratio, binder formulation,and curing time on response variables including unconfined compressive strength (UCS), hydraulic conductivity, porosity, leachate pH, and acid neutralization capacity (ANC) of the s/s products. Results show that all factors had significant effects on the properties of the s/s products. Drill cuttings and HCFA addition both reduced UCS, but HCFA improved hydraulic conductivity, relative to CEM 1 only s/s products. Drill cuttings addition had little effect on the ANC of products prepared with CEM 1 only, and improved that of products containing HCFA. Management options assessment based on performance criteria adapted from regulatory and other guidance suggests that the s/s products could find application as controlled low-strength materials, landfill liner, and landfill daily cover. This work demonstrates how a systematic treatability study can be used to develop a s/s operating window for the management of a particular waste type. (C) 2009 Elsevier B.V. All rights reserved.

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