4.7 Article

Nitrate removal from electro-oxidized landfill leachate by ion exchange

期刊

JOURNAL OF HAZARDOUS MATERIALS
卷 164, 期 1, 页码 389-393

出版社

ELSEVIER
DOI: 10.1016/j.jhazmat.2008.08.012

关键词

Landfill leachate treatment; Nitrate removal; Ion exchange; Equilibrium

资金

  1. Spanish Ministry of Environment [546/2006/2-2.5]
  2. Leonardo Torres Quevedo Foundation

向作者/读者索取更多资源

Treatment of landfill leachates by electrochemical oxidation led to the complete removal of chemical oxygen demand and ammonium nitrogen. However, as result of the ammonium oxidation, the partial formation of nitrate ions was observed. Ion exchange technology was investigated as a polishing step in the treatment of landfill leachates. Removal of nitrate from aqueous solutions was studied using two selective anion exchangers: Purolite A 520E and Purolite A 300, under a fixed bed configuration. The following aspects of the ion exchange system were experimentally analyzed: (i) the influence of the presence of other competitive anions in solution, sulfate and chloride, during the loading step, (ii) the breakthrough point and resin saturation as a function of chloride concentration in the feed stream and, (iii) the efficiency of the regeneration step working with NaCl solutions at several concentrations. After a comparison of the experimental results, it was concluded that the resin Purolite A 300 showed a better behavior. Experimental analysis of the equilibrium isotherms made it possible to determine the equilibrium constant (K = 3.21) and the maximum capacity (q(max) = 183 mg g(-1)), important parameters in the design of the treatment process. (C) 2008 Elsevier B.V. All rights reserved.

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