期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 171, 期 1-3, 页码 478-483出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2009.06.027
关键词
Ionic liquids; Degradation products; Advanced oxidation technology
资金
- Polish Ministry of Research and Higher Education [DS 8200-4-0085-9]
Commonly used alkylimidazolium ionic liquids are poorly to negligibly biodegradable, and some are toxic, with the potential to poison typical biological test systems. Therefore, when ionic liquids are present in technological wastewaters they could break through classical wastewater treatment systems into natural waters and become potentially persistent pollutants. A recent study investigating different advanced oxidation processes found that the H2O2/UV System degraded dissolved imidazolium ionic liquids with the greatest efficiency. In the present study, high performance liquid chromatography was coupled with electrospray mass spectrometry to separate, analyse and identify degradation products following the treatment of ionic liquid solutions with H2O2 in the presence of UV irradiation. It was found that hydroxylation in short-chain entities occurred mainly within the ring moiety, whereas in the case of longer alkylated cations, oxidation of the alkyl chain yielded several products. The potential transformation products were identified structurally by MS/MS analysis and are discussed in the light of their putative toxicity and biodegradability. (C) 2009 Elsevier B.V. All rights reserved.
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