Photocatalytic degradation of gaseous 1-propanol using an annular reactor: Kinetic modelling and pathways

Photocatalytic oxidation of airborne contaminants appears to be a promising process for remediation of air polluted by Volatile Organic Compounds (VOCs). In the present work, the photocatalytic oxidation of gaseous 1-propanol has been investigated by using an annular photoreactor. The annular photocatalytic reactor was modelled by a cascade of heightened elementary continuously stirred tank reactors. The influence of several kinetic parameters such as pollutant concentration, incident light irradiance, contact time and humidity content has been studied. The photocatalytic degradation by-products of 1-propanol has been identified in the gas-phase by GC/MS. Propionaldehyde and acetaldehyde were found to be the main gaseous intermediates. Propionaldehyde and acetaldehyde have been taken into account in a two-site model to evaluate the possible competition of adsorption between 1-propanol and its by-products of degradation. A mechanistic pathway is then proposed for the photocatalytic degradation of 1-propanol. (C) 2008 Elsevier B.V. All rights reserved.