期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 169, 期 1-3, 页码 419-427出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2009.03.112
关键词
Metal oxide nanoparticles; Impregnation; Adsorption kinetics; Degradation; 2-Chloroethylethylsulphide (2-CEES)
Alumina nanoparticles in the size range of 2-30 nm and surface area 375 m(2)/g were synthesized using aerogel route and then characterized using N-2-BET, SEM, TEM, XRD, FTIR and TGA techniques. Thereafter, these were impregnated with reactive chemicals and tested for their potential by conducting studies on kinetics of adsorption of 2-chloroethylethylsulphide (2-CEES) under static conditions. Kinetics was studied using linear driving force and Fickian diffusion model. The kinetics parameters such as equilibration constant, equilibration capacity, diffusional exponent and adsorbate-adsorbent interaction constant were also determined. AP-Al2O3 with 10% impregnation of MoVPA (V-3) and NaOH showed the maximum (574 mg/g) and minimum (88 mg/g) uptake of 2-CEES among impregnated systems respectively. All impregnated systems except NaOH impregnation showed the values of diffusional exponent to be <0.5, indicated the diffusion mechanism to be Fickian, whereas AP-Al2O3 with and without NaOH impregnation showed the diffusional mechanism to be anomalous. Hydrolysis and dehydrohalogenation reactions (identified using GC/MS technique) were found to be the route of degradation of 2-CEES. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.
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