Article
Chemistry, Physical
Dhananjay Dey, Saikat Kumar Seth, T. P. Mohan, Deepak Chopra
Summary: This manuscript comprehensively examines four triazole derivatives through various computational analyses, such as Hirshfeld surface and fingerprint analysis, PIXEL energy, lattice energy, AIM topological analysis, and NCI plots. The results provide insights into the noncovalent interactions and crystal packing stabilization of these structures. The study also analyzes the electronic characteristics and nature of intermolecular interactions in the solid state of the structures.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
C. K. Rajeena, P. C. Sumayya, T. Shalina Begum, K. Muraleedharan
Summary: In this study, the synthesis, crystal structure, and non-covalent interactions of compound 1 were reported. The chemical structure of compound 1 was characterized using spectroscopic techniques and single crystal X-ray diffraction, and its molecular structure was further investigated through DFT/TD-DFT methods. The experimental and theoretical results revealed the existence of amine-imine tautomeric forms in compound 1. Hirshfeld surface and fingerprint analysis demonstrated that the molecular arrangement in the crystal was stabilized by various intermolecular interactions such as hydrogen bonding and pi pi stacking.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
A. Manikandan, M. Dhanalakshmi, L. Guganathan, T. Kokila, M. Santhamoorthy, R. Markkandan, S. C. Kim, C. Balakrishnan
Summary: Two supramolecular complexes of 18-crown-6 with 1,3-dimethylimidazol-3-ium iodide and 1H-benzimidazol-3-ium iodide were successfully synthesized using the slow evaporation solution growth technique. The crystal structures and functional groups were analyzed using single-crystal X-ray diffraction and FT-IR spectral analysis, respectively. The surface morphology of the complexes was observed by scanning electron microscopy. Molecular interactions were analyzed using Hirshfeld surfaces. The research provides insights into the crystal structures and properties of the supramolecular complexes.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Sofia Zazouli, Latifa Laallam, El Mostafa Ketatni
Summary: A new series of benzohydrazide/benzoic acid derivatives were synthesized and characterized by solid-state NMR spectroscopic measurements. The molecular and crystal structures of the compounds were examined using single-crystal X-ray crystallography, revealing the formation of a 3D supramolecular network with specific hydrogen bonding and π-π interactions.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Physical
Joseph Traver, Erica Chenard, Matthias Zeller, Gary L. Guillet, Will E. Lynch, Patrick C. Hillesheim
Summary: A series of ionic compounds based on the dicationic vitamin B1 structure have been synthesized and characterized, with a focus on the thermal stability and solid-state structures of the salts. It was found that an ionic compound with a cyclical anion exhibited higher thermal stability and unique paired dimer interactions among cations. Computational studies were used to further analyze the distinct properties of the compounds.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Multidisciplinary
K. Loganathan, A. Anandan, M. Purushothaman, P. Daniel Jebaraj, K. Thanigaimani, M. Judith Percino, Perumal Venkatesan
Summary: The synthesis and crystal structure of 2-bromo-4,6-bis(dibromoacetyl)resorcinol were reported, and the crystal belongs to the triclinic crystal system with Pi space group. The compound showed various intramolecular and intermolecular interactions, including O-H⋯O, C-H⋯Br/O, and Br⋯Br contacts. The crystal packing was stabilized by these interactions and π-π stacking. The molecular interactions were quantified using PIXEL and Hirshfeld surface analysis, and the Br⋯Br contacts were found to be relatively higher.
STRUCTURAL CHEMISTRY
(2023)
Article
Chemistry, Physical
Alfonso Castineiras, Nuria Fernandez-Hermida, Isabel Garcia-Santos, Lourdes Gomez-Rodriguez, Diego M. Gil, Antonio Frontera
Summary: A new series of 5-acetylbarbituric based thiosemicarbazones have been synthesized and characterized using various methods, with the three-dimensional molecular structures of three compounds determined by single crystal X-ray crystallography. The supramolecular features of the X-ray structure and H-bonding networks observed were also studied, along with unconventional pi-stacking dimers.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Multidisciplinary
Pretam Kumar, Antonio Frontera, Sushil K. Pandey
Summary: The article highlights the important role of Spodium bonding (SpB) in Zn(ii) and Cd(ii) complexes, and presents the synthesis and characterization of two new d(10)-metal dithiophosphate complexes. X-ray crystallography analyses reveal that both complexes are dinuclear with a complex molecular structure.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Crystallography
Essam A. Ali, Rim Bechaieb, Rashad Al-Salahi, Ahmed S. M. Al-Janabi, Mohamed W. Attwa, Gamal A. E. Mostafa
Summary: This study combines experimental and theoretical approaches to explore the crystal growth, structure, and properties of a newly synthesized polymorph. The comprehensive analysis sheds light on the intermolecular interactions, mechanical behavior, and external morphology of the compound.
Article
Chemistry, Multidisciplinary
Marcos Morales-Santana, Sayuri Chong-Canto, Jose Martin Santiago-Quintana, Francisco J. Martinez-Martinez, Efren Garcia-Baez, Alejandro Cruz, Susana Rojas-Lima, Itzia I. Padilla-Martinez
Summary: This work describes the molecular and supramolecular structures of oxalamic acid derivatives and their interactions with different solvents. The polymorphism and stability of these derivatives are explored using computational methods and experimental techniques. The results show that the crystallized solvents play a crucial role in determining the conformation of the derivatives through hydrogen bonding and molecular interactions. This study provides important insights into the understanding and application of oxalamic acid derivatives in crystal engineering and molecular recognition.
Article
Polymer Science
Zouaoui Setifi, Hela Ferjani, Christian Jelsch, Christopher Glidewell, Necmi Dege, Fatima Setifi
Summary: The synthesis, crystal structure, and surface analysis of an Fe(II) complex based on pentadentate N4Py and polynitrile tcnspr ligands were reported. The complex was found to be low-spin Fe(II) complex, with both the coordinated tcnspr molecule and uncoordinated tcnspr anion exhibiting disorder in the crystal structure. The crystal packing was mainly determined by weak intermolecular C-H ellipsis N/S/C hydrogen bonds and stacking interactions.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2021)
Article
Chemistry, Physical
Akhilesh Kumar, Ranjeet Kumar, Rashmi Dubey, Manisha Nidhar, Indresh Verma, Praveen Singh, Ashish Kumar Tewari
Summary: The synthesis and characterization of pyridazine and triazine derivatives containing amide functional group were carried out to study the formation of amide-amide hydrogen-bonded synthons. Supramolecular synthons formations in solid state were investigated using x-ray crystallography and Hirshfeld surface analysis. The crystal structure and Hirshfeld surface analysis revealed that the synthons formation occurred through N-HMIDLINE HORIZONTAL ELLIPSISO interactions and other interactions that stabilized the molecules. In addition, insilico studies were conducted for COX-2 selective inhibitor.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Rumyana Yankova, Ivaylo Tankov, Tanya Tsaneva
Summary: The crystal structure, intermolecular interactions, and nonlinear optical behavior of the ionic liquid Imidazolium Hydrogen Sulfate (ImHS) were investigated for the first time. The combination of experimental (X-ray diffraction) and theoretical (quantum chemical calculations) methods provided important insights into the nonlinear optical properties of ImHS. The formation of hydrogen bonds between the imidazolium cation and hydrogen sulfate anion was found to stabilize the ImHS structure, leading to its highly polarizable nature and making it a promising candidate for nonlinear optical applications.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Multidisciplinary
Ammankallu Sowmya, Gudibande N. Anil Kumar, Sujeet Kumar, Subhas S. Karki
Summary: The crystal structures of three Imidazo [2, 1-b] [1, 3, 4] thiadiazole derivatives were determined by single crystal x-ray diffraction method, with C-H... O hydrogen bonds playing a key role in stabilizing the crystal structures. Analyzing the crystal packing, interaction energies of molecular pairs, molecular electrostatic potential, and nonlinear optical properties shed light on the intermolecular interactions and structural properties of the compounds.
Article
Spectroscopy
Sherzod Zhurakulov, Khayrulla Bobakulov, Akmaljon Tojiboev, Ulli Englert, Ruimin Wang, Irmgard Kalf, Valentina Vinogradova, Bakhodir Tashkhodjaev
Summary: The structure of 3-(3,4-dimethoxyphenylethylamino)-methylidene-1,2,3,9-tetrahydropyrrolo[2,1-b]-quinazolin-9-one hydrochloride has been determined by single-crystal X-ray diffraction at 100 K. The crystallographic study revealed the molecular structure, configuration of the bond, and space group of the crystal.
SPECTROSCOPY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Rahul Soman, Subramaniam Sujatha, Chellaiah Arunkumar
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
(2017)
Article
Chemistry, Multidisciplinary
Chellaiah Arunkumar, Fasalu Rahman Kooriyaden, Subramaniam Sujatha
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
(2017)
Article
Chemistry, Multidisciplinary
Chellaiah Arunkumar, Fasalu Rahman Kooriyaden, Xiaochen Zhang, Subramaniam Sujatha, Jianzhang Zhao
NEW JOURNAL OF CHEMISTRY
(2017)
Article
Chemistry, Inorganic & Nuclear
Fasalu Rahman Kooriyaden, Subramaniam Sujatha, Chellaiah Arunkumar
Article
Chemistry, Multidisciplinary
Jagadeesan Ramesh, Chellaiah Arunkumar, Subramaniam Sujatha
Article
Chemistry, Applied
Monisha Manathanath, Maichong Xie, Chellaiah Arunkumar, Zhonggang Wang, Jianzhang Zhao, Subramaniam Sujatha
Article
Chemistry, Inorganic & Nuclear
Jagadeesan Ramesh, Chellaiah Arunkumar, Subramaniam Sujatha
Article
Chemistry, Organic
Brijesh Chandra, Rahul Soman, B. Sathish Kumar, K. V. Jovan Jose, Pradeepta K. Panda
Article
Chemistry, Multidisciplinary
Diana Mathew, Jagadeesan Ramesh, Santanu Sasidharan, Kannan Subburaj, Prakash Saudagar, Pattiyil Parameswaran, Subramaniam Sujatha
Summary: A (2) B (2) porphyrin bearing 2/3-thienyl and 2-pyridyl moieties and its dicationic derivatives were synthesized in reasonably good yield. The synthesized compounds were characterized by various spectroscopic techniques, electrochemical studies, and thermogravimetric analysis. DNA interaction studies and antimicrobial properties of the dicationic derivatives were investigated, revealing significant findings about their binding with DNA and growth inhibitory effect against bacteria.
Review
Biochemistry & Molecular Biology
Diana Mathew, Subramaniam Sujatha
Summary: The advancement of porphyrins as artificial nucleases has shown potential therapeutic applications. Through chemical modifications of the porphyrin macrocycle, improvements have been made to enhance spectroscopic properties and adapt them as artificial receptors for molecule recognition. Research in the past two decades has focused on porphyrin-DNA interactions, evolving from simple to more complex entities. Specific emphasis has been placed on the effects of porphyrins on DNA cleavage potency.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2021)
Article
Chemistry, Organic
Rahul Soman, Brijesh Chandra, Ishfaq A. Bhat, B. Sathish Kumar, Sk Saddam Hossain, Sridatri Nandy, K. V. Jovan Jose, Pradeepta K. Panda
Summary: The study demonstrates the direct fabrication of a series of A(2)B- and A(3)-type B(III)-subchlorins using a novel method, which may have potential applications as photosensitizers in photodynamic therapy (PDT). The results show that the absorption and emission behaviors of the subchlorins can be tuned by introducing different electron-rich or electron-deficient substituents. Furthermore, it was found that certain subchlorins efficiently generate singlet oxygen, highlighting their potential in PDT.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Organic
Jodukathula Nagamaiah, Arnab Dutta, Narendra Nath Pati, Sameeta Sahoo, Rahul Soman, Pradeepta K. Panda
Summary: In this study, we successfully designed and synthesized 3,6,13,16-tetrapropylporphycene for the first time as its alkyl analogue. The substituent effect was found to be more intense than previously reported tetrapropylporphycenes, and the compound showed moderate fluorescence and the ability to complex with divalent metal ions. The Pd(II) complex and freebase beta-tetrabromoporphycene exhibited efficient singlet oxygen generation, indicating their potential application as photosensitizers in photodynamic therapy.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Monisha Manathanath, Santanu Sasidharan, Prakash Saudagar, Unnikrishnan Gopalakrishna Panicker, Subramaniam Sujatha
Summary: Recent advancements in porphyrin-based photodynamic therapy have revolutionized medicinal chemistry by offering effective solutions for serious diseases like cancer. In this study, a triazine-based porphyrin derivative was synthesized using a mild and effective microwave-assisted method, and its inhibitory activity against cancer cells was evaluated. The derivatives showed better inhibitory activity under light, while being non-toxic to normal cells. Confocal microscopy confirmed the cellular uptake of the compounds and the singlet oxygen generation efficiency indicated the superior inhibitory activity of the zinc derivative.
Article
Chemistry, Inorganic & Nuclear
Diana Mathew, Yingqi Hu, Jianzhang Zhao, Chellaiah Arunkumar, Subramaniam Sujatha
Article
Chemistry, Inorganic & Nuclear
Xianda Wu, Minghong Chen, Shuiyun Zheng, Fu-Sheng He, Jie Wu
Summary: Here, we report a new method for synthesizing sulfilimines through an iron-catalyzed reaction between sulfenamides and 2,2,2-trifluor-diazoethane. This protocol features operational simplicity, mild conditions, and can be conducted in open air, providing a facile approach to trifloromethylated sulfilimines in moderate to good yields.
JOURNAL OF FLUORINE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Ita Hajdin, Romana Pajkert, Haibo Mei, Jianlin Han, Gerd-Volker Roeschenthaler
Summary: A catalyst- and solvent-free 1,3-dipolar cycloaddition reaction using a bench-stable diazo reagent has been developed to obtain a series of novel 3H-pyrazoles bearing difluoromethyl phosphonate unit in moderate-to-excellent yields. This method provides an efficient and easy route to synthesize valuable compounds.
JOURNAL OF FLUORINE CHEMISTRY
(2024)