期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 130, 期 2, 页码 175-196出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2008.09.012
关键词
Donor acceptor halogenostyrylbenzonitriles; HWE approach; Heck coupling; Halogen bonding; Co-crystals; SHG; Crystal structure
The syntheses and crystal structures of a series of fluoro-substituted halogeno (Cl, Br, I)-cyano-stilbenes containing donor and acceptor groups (D-pi-A) are reported. These molecules show a tendency to form antiparallel chain-like structures and herringbone packing, crystallising predominantly in a centric space group. However, second harmonic generation measurements bear evidence for orientational disorder leading to partial polar order below the ordinary X-ray structure determination limit. Some co-crystals are isostructural with their components. The non-fluoro as well as the halogeno-fluoro substituted components of co-crystals seem to impose their crystal structure on the complementary fluoro- or cyano-fluoro Substituted components. Co-crystallization enhanced the deviation from centrosymmetry. (C) 2008 Published by Elsevier B.V.
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