期刊
JOURNAL OF ENVIRONMENTAL SCIENCES
卷 23, 期 7, 页码 1211-1218出版社
SCIENCE PRESS
DOI: 10.1016/S1001-0742(10)60534-7
关键词
silica fume; Fe-0 nanoparticles; stability; Cr(VI) removal; transport
资金
- National Natural Science Foundation of China [40971254]
- National Youth Science Foundation of China [20907023]
Effective in situ remediation of Cr(VI) in groundwater requires the successful delivery of reactive iron particles to the subsurface. Fe-0 nanoparticles (20-110 nm diameter) supported on silica fume were synthesized by borohydride reduction of an aqueous iron salt in the presence of a support material. The experimental result showed that attachment of Fe-0 nanoparticles on the commercial available sub-micrometer silica fume prevented them from aggregation while maintaining the particle reactivity. When the Fe-0 concentration was 0.4 g/L, 88.00% of 40 mg/L Cr(VI) was removed by silica fume-supported Fe-0 nanoparticles (SF-Fe-0) in 120 min, 22.55% higher than unsupported Fe-0. Furthermore, transport experiments confirmed that almost all unsupported Fe-0 was retained, whereas 51.50% and 38.29% of SF-Fe-0 were eluted from the vertical and horizontal sand column, respectively. Additionally, the effect of solution ionic strength on the transport ability of SF-Fe-0 was evaluated. The result showed that increase in the salt concentration led to a decrease in the mobility and also the divalent ion Ca2+ had a greater effect than that of monovalent ion Na+.
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