Article
Environmental Sciences
Maozhong Zheng, Gang Li, Yongle Hu, Jerome Nriagu, Eric Fru Zama
Summary: The study found that arsenic pollution does not alter the distribution of elements like iron, manganese, copper, and zinc in rice grains, with arsenic mainly affecting sulfur, copper, and zinc in rice caryopsis.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Caroline Bissardon, Olivier Proux, Salvatore Andrea Gazze, Odile Filhol, Benoit Toubhans, Lucie Sauzeat, Sylvain Bouchet, Aled R. Lewis, Thierry Maffeis, Jean-Louis Hazemann, Sam Bayat, Peter Cloetens, R. Steven Conlan, Laurent Charlet, Sylvain Bohic
Summary: This study investigated the effects of sub-toxic concentrations of functionalized selenium nanoparticles on prostate cancer cells and their intracellular localization and fate. The results showed that monodisperse selenium nanoparticles capped with bovine serum albumin could slow down the migration capacity of aggressive prostate cancer cells compared to polydisperse selenium nanoparticles capped with chitosan. The nanoparticles were found to interact with mitochondria in the cells. These findings provide new insight for further research on the cytotoxic mechanisms of selenium nanoparticles.
Article
Environmental Sciences
Pauline Courtois, Agnieszka Rorat, Sebastien Lemiere, Clement Levard, Perrine Chaurand, Anna Grobelak, Christine Lors, Franck Vandenbulcke
Summary: Research on earthworms exposed to silver-contaminated soil revealed that different forms of silver had varying effects on survival, but exhibited similar speciation and content in the earthworms at the end of exposure, indicating biotransformation. X-ray micro-computed tomography images showed silver preferentially accumulated in specific tissues, suggesting efficient bioaccumulation with a regulatory mechanism in E. fetida. The competition between silver and copper, along with the speciation of internal silver, indicates a link to thiol-rich proteins like metallothioneins involved in metal sequestration and detoxification.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Thermodynamics
Colin Banyon, Matthew J. Montgomery, Hyunguk Kwon, Alan L. Kastengren, Lisa D. Pfefferle, Travis Sikes, Yuan Xuan, Charles S. McEnally, Robert S. Tranter
Summary: This study presents high-fidelity temperature field measurements of heavily-sooting ethylene/air flames using x-ray fluorescence (XRF) measurements. The challenges faced by conventional optical diagnostics have been overcome by implementing the XRF method with a fluorescent agent. The results demonstrate the efficacy and cost-effectiveness of this method in accurately interpreting the experimental signals.
COMBUSTION AND FLAME
(2023)
Article
Computer Science, Artificial Intelligence
A. Rakotondrajoa, M. Radtke
Summary: This study utilized artificial neural networks (ANNs) for quantifying x-ray fluorescence measurements, using Monte Carlo simulation to generate training data and demonstrating the ability to generate additional data through ANN. Emphasis was placed on comparing simulated and experimental data comparability and reducing the influence of deviations, while also describing the search for optimal hyperparameters.
MACHINE LEARNING-SCIENCE AND TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Xueying L. Quinn, Rishi E. Kumar, Moses Kodur, Deniz N. Cakan, Zhonghou Cai, Tao Zhou, Martin V. Holt, David P. Fenning
Summary: Europium as a B-site additive in CsPbBr3 perovskite crystals reduces microstrain, improves photoluminescence yield, and enhances X-ray hardness. Despite variations in the degree of europium incorporation locally, the findings show promise for europium as an additive in perovskite optoelectronic devices.
ADVANCED OPTICAL MATERIALS
(2021)
Article
Geosciences, Multidisciplinary
Y. Xiang, P. J. Lam, J. M. Lee
Summary: The study found that the oxidation state of particulate manganese in the surface Arctic Ocean is related to the sampling time, with AOS <2.4 during the day and >3.0 at night. It is hypothesized that a light-dependent redox cycle between dissolved and particulate manganese exists in the surface Arctic Ocean.
GEOPHYSICAL RESEARCH LETTERS
(2021)
Article
Chemistry, Physical
Bura Sindhupakorn, Pinit Kidkhunthod
Summary: This study examined structural changes in subchondral bone samples from osteoarthritic knee patients compared to controlled patients, using Synchrotron-based X-ray fluorescence and X-ray absorption spectroscopy techniques. The results revealed lower phosphorus content in older OA patients, leading to lower Ca-P proportions associated with osteoporosis. The majority of bone samples exhibited an amorphous structure of calcium-phosphate.
RADIATION PHYSICS AND CHEMISTRY
(2021)
Review
Metallurgy & Metallurgical Engineering
Youhong Peng, Kesong Miao, Wei Sun, Chenglu Liu, Hao Wu, Lin Geng, Guohua Fan
Summary: Characterizing the microstructure and deformation mechanism of metallic materials is crucial for understanding the microstructure-property relationship. Advanced synchrotron radiation facilities have enabled non-destructive visualization of full-field structural information in three dimensions, contributing to significant progress in recent decades. Future innovations in next-generation synchrotron radiation and emerging technologies hold great potential for further advancements in material characterization.
ACTA METALLURGICA SINICA-ENGLISH LETTERS
(2022)
Article
Agronomy
Jiali Yan, Zhong Tang, Matthew Fischel, Peng Wang, Matthew G. Siebecker, Mark G. M. Aarts, Donald L. Sparks, Fang-Jie Zhao
Summary: This study aims to screen Noccaea caerulescens lines with high cadmium phytoextraction efficiency and investigate differences in cadmium species and distribution in the leaves. The results showed that there are wide variations in biomass production and cadmium accumulation capacity among different lines, and cadmium-thiol complexes play a crucial role in cadmium detoxification.
Article
Biochemistry & Molecular Biology
Antony van der Ent, Martin D. de Jonge, Guillaume Echevarria, Mark G. M. Aarts, Jolanta Mesjasz-Przybylowicz, Wojciech J. Przybylowicz, Dennis Brueckner, Hugh H. Harris
Summary: This study used synchrotron X-ray fluorescence tomography techniques and planar elemental X-ray imaging to investigate the tissue distribution of nickel (Ni) and zinc (Zn) during seed germination of Noccaea caerulescens. The results showed that Ni and Zn were primarily located in the cotyledons and did not translocate during germination.
Review
Chemistry, Physical
Benjamin Rotonnelli, Marie-Sophie Dias Fernandes, Fabrice Bournel, Jean-Jacques Gallet, Benedikt Lassalle-Kaiser
Summary: Water electrolysis for hydrogen production provides a convenient and carbon-free option to regulate the intermittency of renewable energy sources. Efficient catalysts based on noble metals are currently used for large-scale production, but efforts are being made to reduce catalyst usage while maintaining their efficiency. Fundamental studies on catalyst structure, reaction intermediates, and failure modes support these efforts. Synchrotron-based techniques, such as X-ray photoelectron and X-ray absorption spectroscopies, can provide valuable information during the reaction. This article gives an overview of these techniques and their application to water electrolysis.
CURRENT OPINION IN ELECTROCHEMISTRY
(2023)
Article
Materials Science, Paper & Wood
Philip D. Evans, Hiroshi Matsunaga, Dengcheng Feng, Michael Turner, Richard W. Henley, Cameron M. Kewish
Summary: Turpentine wood is known for its resistance to marine borers, believed to be due to its high silica content and presence of unknown compounds. Recent studies have revealed a diverse range of biocidal heavy metals in its heartwood, with concentrations reaching toxic levels for mollusk embryos and larvae. These inorganic components may contribute to the wood's marine borer resistance.
JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Cyril Besnard, Ali Marie, Sisini Sasidharan, Petr Buck, Jessica M. Walker, Julia E. Parker, Thomas E. J. Moxham, Benedikt Daurer, Burkhard Kaulich, Majid Kazemian, Richard M. Shelton, Gabriel Landini, Alexander M. Korsunsky
Summary: This study characterises human dental enamel caries using synchrotron nanoscale imaging techniques combined with scanning electron microscopy. The research reveals the nanoscale variation in chemistry and structure of carious enamel and demonstrates the importance of advanced correlative imaging in investigating the complex structure-composition relationships in nano-materials.
MATERIALS & DESIGN
(2022)
Article
Engineering, Environmental
Vijay Kumar Garg, Ankush Tanta, Arun Lal Srivastav, M. K. Tiwari, Ajay Sharma, Varinder Singh Kanwar
Summary: Pollutants released from pharmaceutical, steel, paper, and battery industries into water cause irreparable damage to the biotic system by entering the natural ecosystems and human food chain. Monitoring and determining heavy metal levels in water are crucial for human beings. In this study, TXRF spectrometry technique was used to assess the contaminant levels in water samples from an industrial area. The elemental concentrations were compared to the guidelines from WHO and BIS, and water quality parameters were assessed. The results showed that some water samples were unfit for drinking with high levels of lead and other heavy metals.
WATER ENVIRONMENT RESEARCH
(2022)
Article
Environmental Sciences
Prasun Goswami, Keerthi S. Guruge, Rumi Tanoue, Yukino A. Tamamura, K. B. S. N. Jinadasa, Kei Nomiyama, Tatsuya Kunisue, Shinsuke Tanabe
Summary: This study investigated the presence of pharmaceutically active compounds (PACs) in wastewater from hospitals and adjacent surface waters in Sri Lanka, revealing variations in removal rates among facilities and potential ecological risks posed by PACs to aquatic organisms. The findings suggest ineffective treatment processes and increased PAC concentrations in effluents, highlighting the importance of monitoring and addressing pharmaceutical pollution in water bodies.
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY
(2022)
Article
Environmental Sciences
Cesar Augusto Paz-Villarraga, Italo Braga Castro, Gilberto Fillmann
Summary: Antifouling paints incorporate biocides to prevent the growth of unwanted organisms, but these biocides also impact non-target organisms and ecosystems. This study examined the occurrence and concentrations of biocides in antifouling paint formulations worldwide. The results identified 25 active ingredients currently used, with cuprous oxide, copper pyrithione, zinc pyrithione, zineb, DCOIT, and cuprous thiocyanate being the most frequent ones.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Environmental Sciences
Muryllo Santos Castro, Larissa Cristine Carvalho Penha, Thamires Alexsandra Torres, Marianna Basso Jorge, Luis Fernando Carvalho-Costa, Gilberto Fillmann, Ricardo Luvizotto-Santos
Summary: The study found that even at the lowest dose tested (0.35 μg g(-1)), chlorothalonil showed genotoxic and mutagenic effects, which increased in a dose-dependent manner with higher doses. This evidence suggests that the compound should be banned due to potential hazards to aquatic ecosystems and human health, outweighing any benefits to food production.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Biochemical Research Methods
Kohki Takaguchi, Sumika Ono, Rumi Tanoue, Tatsuya Kunisue, Shinsuke Tanabe, Kei Nomiyama
Summary: Thyroid hormones play a critical role in regulating biological processes, and determination of deiodinated TH metabolites in key organs can help understand tissue-specific TH metabolism and homeostasis. A highly sensitive method was developed to determine six THs in dog brain and liver, which was successfully applied to analyze THs in dogs exposed to PCBs and revealed alterations in peripheral TH metabolism caused by environmental pollutants.
JOURNAL OF CHROMATOGRAPHY A
(2022)
Article
Environmental Sciences
Bruno Galvao de Campos, Mayana Karoline Fontes, Paloma Kachel Gusso-Choueri, Gabriela Pustiglione Marinsek, Caio Rodrigues Nobre, Beatriz Barbosa Moreno, Fiamma Eugenia Lemos Abreu, Gilberto Fillmann, Renata de Britto Mari, Denis Moledo de Souza Abessa
Summary: The study on the sublethal effects of DCOIT on the neotropical oyster revealed that exposure to environmentally relevant concentrations of DCOIT can trigger oxidative stress and histopathological abnormalities in gills and digestive glands, suggesting potential negative impacts on C. brasiliana.
MARINE POLLUTION BULLETIN
(2022)
Article
Environmental Sciences
Russell G. Uc-Peraza, Italo B. Castro, Gilberto Fillmann
Summary: Despite efforts by international organizations to ban TBT-based antifouling paints and trade of tributyltin, this study shows that the situation persists and may have a more global distribution than previously thought.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Astronomy & Astrophysics
D. S. Svinkin, K. Hurley, A. Ridnaia, A. L. Lysenko, D. D. Frederiks, S. Golenetskii, A. E. Tsvetkova, M. Ulanov, A. Kokomov, T. L. Cline, I Mitrofanov, D. Golovin, A. Kozyrev, M. Litvak, A. Sanin, A. Goldstein, M. S. Briggs, C. Wilson-Hodge, E. Burns, A. von Kienlin, X-L Zhang, A. Rau, V Savchenko, E. Bozzo, C. Ferrigno, S. Barthelmy, J. Cummings, H. Krimm, D. M. Palmer, A. Tohuvavohu, K. Yamaoka, M. Ohno, Y. Fukazawa, Y. Hanabata, T. Takahashi, M. Tashiro, Y. Terada, T. Murakami, K. Makishima, W. Boynton, C. W. Fellows, K. P. Harshman, H. Enos, R. Starr, J. Goldsten, R. Gold, A. Ursi, M. Tavani, A. Bulgarelli, C. Casentini, E. Del Monte, Y. Evangelista, M. Galli, F. Longo, M. Marisaldi, N. Parmiggiani, C. Pittori, M. Romani, F. Verrecchia, D. M. Smith, W. Hajdas, S. Xiao, C. Cai, Q. B. Yi, Y. Q. Zhang, S. L. Xiong, X. B. Li, Y. Huang, C. K. Li, S. N. Zhang, L. M. Song, C. Z. Liu, X. Q. Li, W. X. Peng, I Martinez-Castellanos
Summary: This article presents the catalog of 199 short-duration gamma-ray bursts detected by the Konus-Wind experiment, providing comprehensive IPN localization data on these events, including probability sky maps.
ASTROPHYSICAL JOURNAL SUPPLEMENT SERIES
(2022)
Article
Engineering, Environmental
Russell Giovanni Uc-Peraza, Victor Hugo Delgado-Blas, Jaime Rendon-von Osten, Italo Braga Castro, Maira Carneiro Proietti, Gilberto Fillmann
Summary: This study assessed the levels of various chemicals and the occurrence of imposex in several gastropod species in sites under the influence of maritime activities along the coastal zone of the Yucatan Peninsula, Mexico. The results showed that some sites had high levels of chemicals exceeding international quality guidelines and imposex was detected in certain species, indicating a potential threat to marine life.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Astronomy & Astrophysics
Tsubasa Tamba, Hirokazu Odaka, Aya Bamba, Hiroshi Murakami, Koji Mori, Kiyoshi Hayashida, Yukikatsu Terada, Tsunefumi Mizuno, Masayoshi Nobukawa
Summary: A simulation-based method of spectral analysis has been developed for pile-up-affected data of X-ray CCDs. The method accurately corrects pile-up effects and is applicable to different types of CCDs.
PUBLICATIONS OF THE ASTRONOMICAL SOCIETY OF JAPAN
(2022)
Article
Ecology
Takashi Kunito, Hiroaki Kurita, Masaki Kumori, Katsutoshi Sakaguchi, Seiya Nishizawa, Kazuki Fujita, Hitoshi Moro, Kozue Sawada, Yuichi Miyabara, Hideshige Toda, Kazunari Nagaoka, Yuichi Ishikawa
Summary: This study shows that microorganisms allocate more resources to synthesis of arylsulfatase, an enzyme involved in sulfur acquisition, in soils with lower concentration of soluble and adsorbed sulfate. The ecoenzymatic stoichiometry could be useful for evaluating soil sulfur plant-availability.
EUROPEAN JOURNAL OF SOIL BIOLOGY
(2022)
Article
Environmental Sciences
Mirta L. Menone, Mauricio Diaz-Jaramillo, Francesca Mitton, Daniela S. Garanzini, Patricia Gomes Costa, Leonardo Lupi, German Lukaszewicz, Mariana Gonzalez, Solange Jara, Karina S. B. Miglioranza, Gilberto Fillmann, Ricardo O. Barra
Summary: Estuarine saltmarshes in South America are affected by chemical and petrochemical industries, resulting in the presence of non-essential trace elements (NTEs) and polycyclic aromatic hydrocarbons (PAHs) in sediments. The native cordgrass Spartina densiflora exhibits different responses to pollution in different saltmarsh areas, with the ability to increase NTEs levels in rhizosediments and bioconcentrate Cd in roots. However, general translocation of contaminants is not observed. Conversely, PAHs contents are higher in cordgrass tissues, bulk sediments, and rhizosediments, with lower levels in rhizosediments compared to bulk sediments. The study highlights the capacity of S. densiflora to retain, remove, and/or translocate priority contaminants depending on their chemical characteristics and the level of contamination.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Environmental Sciences
Russell Giovanni Uc-Peraza, Victor Hugo Delgado-Blas, Jaime Rendon-von Osten, Italo Braga Castro, Maira Carneiro Proietti, Gilberto Fillmann
Summary: The study assessed the potential health risk of ingesting organotin compounds in seafood from the Yucatan Peninsula. Organotin compounds were detected in all samples, but the estimated intake levels were below the tolerable daily intake established by EFSA. Therefore, seafood consumers in the Yucatan Peninsula are unlikely to be at risk.
Article
Multidisciplinary Sciences
Takashi Kunito, Shota Hibino, Hirotaka Sumi, Kozue Sawada, Ho-Dong Park, Kazunari Nagaoka
Summary: We characterized the bacterial and fungal communities in forest soils using CLPP and PCR-DGGE analysis. The results showed clear separation between the O and A horizons in terms of CLPP and DGGE profiles, except for the fungal CLPP. No significant links were observed between the O and A horizons, suggesting different factors influencing the microbial communities. However, there were significant couplings between bacterial and fungal profiles within each horizon, indicating common factors shaping the communities. The potential functioning was not strongly associated with the composition of the microbial community.
Article
Plant Sciences
Kozue Sawada, Takashi Kunito, Tetsuhiro Watanabe, Natsuko Kitagawa, Han Lyu, Ho Lam Nguyen, Koki Toyota, Shinya Funakawa
Summary: The addition of phosphorus has minimal effect on enhancing the mineralization of preexisting soil organic carbon. However, in phosphorus-limited tropical forest soils with nitrogen-fixing trees, the microbial phosphorus mining can drive positive priming effects when a small amount of glucose is added. The results indicate that positive priming effects occur through microbial phosphorus mining, independent of phosphatase hydrolysis of organic phosphorus esters, under phosphorus limitation in nitrogen-rich and phosphorus-poor tropical forest soils.
SOIL SCIENCE AND PLANT NUTRITION
(2023)
Article
Soil Science
Kozue Sawada, Yoshiyuki Inagaki, Soh Sugihara, Takashi Kunito, Jun Murase, Koki Toyota, Shinya Funakawa
Summary: Converting natural forests to coniferous plantations in temperate regions impacts soil nitrogen cycling, but the belowground microbial communities responsible for these changes are poorly understood, especially in coniferous-dominated forest ecosystems. In this study, we examined the effects of converting natural forests to pure cedar plantations on soil N cycling and microbial communities using high-throughput amplicon sequencing technique in two areas with different acidity levels. Our results showed that the conversion increased inorganic N content and altered the relative abundances of fungal and bacterial communities, as well as their interactions with ammoniaoxidizing archaeal abundances, leading to higher nitrate N content in cedar plantations, particularly in less acidic areas.
APPLIED SOIL ECOLOGY
(2023)