期刊
JOURNAL OF ELECTRONIC MATERIALS
卷 38, 期 7, 页码 1423-1426出版社
SPRINGER
DOI: 10.1007/s11664-008-0643-9
关键词
Clathrate; electrical resistivity; carrier concentration; Ba8Ga16Ge30; thermoelectricity
Polycrystalline Ba8Ga (x) Ge46-x exhibits promising thermoelectric performance with the figure of merit ZT close to that of single crystals. Polycrystalline Ba8Ga (x) Ge46-x is promising for applications, but reproducibility and thermal stability of thermoelectric properties need to be demonstrated. Polycrystalline samples of Ba8+dGa (x) Ge46-x -type clathrates (15.0 a parts per thousand currency sign x a parts per thousand currency sign 16.8 with varied nominal Ga content and d = 0 or 0.2) were prepared by direct reaction of the elements, followed by ball milling and hot pressing. Trace Ge impurity was observed (< 1.0 wt.%) depending on the synthesis method. The electrical resistivity was stable in measurements up to 1000 K, regardless of Ge impurity. However, measurements to 1050 K resulted in irreversible increase in carrier concentration while the carrier mobility remained unchanged.
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