期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 688, 期 -, 页码 113-117出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2012.09.042
关键词
Lithium-ion batteries; Cathode material; Lithium nickel manganese oxides; Nanorods; Diffusion
资金
- Programs of National 973 [2011CB935900]
- NSFC [21231005]
- 111 Project [B12015]
- Tianjin High-Tech [10SYSYJC27600, 10ZCGHHZ01200]
We report on the synthesis of ordered spinel LiNi0.5Mn1.5O4 nanorods (LNMO-NRs) and their application as high-rate cathode materials of lithium-ion batteries. Ordered spinel LNMO-NRs were prepared by a simple self-support template method followed by a solid-state reaction. The as prepared LNMO-NRs displayed uniform one dimensional (1D) nanostructure with the diameters of about 100 nm and the lengths around 2-3 mu m. X-ray diffraction and Raman spectroscopy showed that the products existed in pure P4(3)32 phase. When the as-prepared LNMO-NRs were applied as the cathode materials for lithium ion batteries, they exhibited a superior high-rate capability (135 mA h g(-1) at 1 C, 120 mA h g(-1) at 20 C) and a good cyclability (at 20 C with a high retention of 90% after 80 cycles). The durable high-rate capability was attributed to the one-dimensional nanostructure with the ordered phase that shows fast Li-intercalation kinetics and good structural stability. (C) 2012 Elsevier B.V. All rights reserved.
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