期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 704, 期 -, 页码 75-79出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2013.06.002
关键词
N,N-dimethyl-p-phenylenediamine; Cyclic voltammetry; Mechanistic studies; Electrochemical oxidation; Organic electrochemistry
资金
- Bu-Ali Sina University Research Council
- Center of Excellence in Development of Chemical Methods (CEDCM)
- Research Council of Payame Noor University
The electrochemical behavior of N,N-dimethyl-p-phenylenediamine (DMPD) was studied in aqueous media at various pH regions using cyclic voltammetry. Diagnostic criteria of cyclic voltammetry indicate mechanism diversity in anodic oxidation by varying pH. It is confirmed that the electrochemical oxidation of DMPD as an infrequent real case occurs via various mechanistic disciplines such as CE at pH 0, EE at pH 3-6, ECE in basic solutions and simple E at other pHs. (C) 2013 Elsevier B.V. All rights reserved.
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