4.3 Article

Synthesis of Pt Nanoparticles in Oil-in-Water Microemulsions: Phase Behavior and Effect of Formulation Parameters on Nanoparticle Characteristics

期刊

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
卷 32, 期 12, 页码 1765-1770

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/01932691.2011.616170

关键词

Nano-reactor; nanoparticle synthesis; nonionic microemulsion; o/w microemulsions; Pt nanoparticles

资金

  1. CSIC
  2. Ministerio de Ciencia e Innovacion (MICIN, Spain) [CTQ2008-01979]
  3. Generalitat de Catalunya [2009-SGR-00961]

向作者/读者索取更多资源

Pt nanoparticles were synthesized in oil-in-water (o/w) microemulsions, in contrast to the typically used water-in-oil microemulsion method. The new strategy implies the use of a Pt organometallic precursor (1,5-cyclooctadiene dimethyl platinum (II)), dissolved in nanometre-scale oil droplets, stabilized by surfactant, and dispersed in a continuous aqueous phase. Three different nonionic microemulsion systems were used. Characterization studies demonstrate that small, nanocrystalline Pt nanoparticles were obtained. The particle size and agglomeration was dependant on the microemulsion system used and its composition. The obtained results demonstrate the feasibility of this approach for the controlled synthesis of Pt nanoparticles with potential for catalytic purposes.

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