期刊
JOURNAL OF CRYSTAL GROWTH
卷 373, 期 -, 页码 96-101出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jcrysgro.2012.11.043
关键词
Cobalt complex; Metal organic framework (MOE); Carbon dioxide; Calcium carbonate
资金
- Korea Institute of Geoscience and Mineral resources (KIGAM)
- Ministry of Knowledge Economy of Korea
A new biomimetic complex (Co-BBP) that mimics the active site of carbonic anhydrase (CA) was prepared by the coordination of cobalt (II) with 2, 6-bis(2-benzimidazolyl) and was encapsulated into a metal organic framework (Co-BBP@Tb-MOF). Carbon dioxide (CO2) sequestration was carried out via an in vitro mineralization approach using these biomimetic catalysts. The biomimetic catalysts were expected to enhance CO2 hydration and calcium carbonate (CaCO3) crystallization based on the same mechanism as that of CA. (C) 2012 Elsevier B.V. All rights reserved.
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