期刊
JOURNAL OF CRYSTAL GROWTH
卷 326, 期 1, 页码 9-13出版社
ELSEVIER
DOI: 10.1016/j.jcrysgro.2011.01.041
关键词
Epitaxial growth; Pulsed laser deposition; CuCrO2; Delafossite; Transparent conducting oxides
资金
- Priority Research Centers Program
- Mid-career Researcher Program
- Korea government (MEST) [2009-0093819, 2007-0056848, 2009-0063397, 2009-0063394]
- Anti-aging and well-being Research Center of MEST
- National Research Foundation of Korea [2007-0056848] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We report an investigation of the structural properties of CuCr0.95Mg0.05O2 films on c-plane sapphire substrates using pulsed laser deposition. The thin films were grown at different temperatures of 500, 600, and 700 degrees C with an oxygen partial pressure of 10 mTorr. c-axis oriented epitaxial CuCr0.95Mg0.05O2 thin films on c-plane sapphire substrates with an in-plan 30 degrees rotation were obtained. The sixfold rotational symmetry in the pole figures from the (0 1 2) plane indicates that there are two different types of crystal grains in which the a-axes rotate by 60 degrees with respect to each other around the c-axis. The reason for the 30 degrees rotation is assumed to be the presence of the similar to 10% mismatch of oxygen distance between the c-plane sapphire substrate and the CuCr0.95Mg0.05O2 on the c-plane. The epitaxial crystallographic relationship between CuCr0.95Mg0.05O2 and Al2O3 was (0 00 6)CuCrO2//(0 00 3)Al2O3 and [1 0 -1 0]CuCrO2//[1 1 -2 0]Al2O3. The presence of twins in the films and the surface morphology were investigated using transmission electron microscopy and scanning electron microscopy, respectively. (C) 2011 Elsevier B.V. All rights reserved.
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