期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 65, 期 5, 页码 795-812出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2012.662592
关键词
Hydrogen bonds; Crystal engineering; Cyclic voltammetry
资金
- UGC [36-28/2008 (SR)]
- CSIR, New Delhi [01(2451)/11/EMR-II]
A series of nickel(II) complexes, namely [Ni(L)(2)] (1), [Ni(L)(HL)](ClO4)(H2O) (2), [Ni(HL)(bipy)(H2O)](NO3)(ClO4)(H2O) (3), and [Ni(HL)(dien)](ClO4)(2)(H2O) (4) have been synthesized with Schiff base (L) derived from 2-pyridinecarboxaldehyde and benzoylhydrazine. The elemental analyses of the complexes indicate stoichiometry ML2 and M(L)(B), where L = N-[(1)-pyridin-2-ylmethylidene]benzohydrazide, B = diethylenetriamine/2,2'-bipyridine. L is a deprotonated as well as neutral tridentate ligand. Single-crystal X-ray structures of 1-4 reveal distorted octahedral geometry in the complexes. The molecules are connected by various hydrogen-bonding interactions. Magnetic susceptibility measurements at room temperature were 2.79-2.91 MB. The electrochemical behavior, superoxide dismutase, and antibacterial activities of these complexes were made by cyclic voltammetry, the alkaline DMSO-nitro blue tetrazolium chloride assay, and the paper disc diffusion method, respectively.
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