Article
Environmental Sciences
Karanpal Singh, Nancy, Harpreet Kaur, Pushpender Kumar Sharma, Gurjinder Singh, Jagpreet Singh
Summary: The study synthesized undoped and Cobalt-doped zinc oxide nanoparticles (Co doped ZnO NPs) and confirmed the incorporation of the Co dopant through spectroscopic and microscopic techniques. The Co-doped ZnO NPs showed a red shift in the UV-absorption spectra and a decrease in band gap value, indicating successful integration of Co2+ ions into the ZnO matrix. The synthesized NPs exhibited excellent photocatalytic and antimicrobial activity, with 1% Co-doped ZnO showing the highest photocatalytic efficiency.
Article
Green & Sustainable Science & Technology
Hongjuan Qin, Zhen Wang, Shaocong Yang, Wenqiang Jiang, Yawei Gu, Jiachuan Chen, Guihua Yang
Summary: A novel type of iron-based nanoparticles decorated with cuprous sulfide and cuprous oxide was developed for the degradation of 2,4-dichlorophenol. The catalyst exhibited excellent catalytic performance through adsorption, Fenton-like oxidation, and photocatalytic processes. The research provides a promising approach for the treatment of chlorophenols polluted water.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Engineering, Environmental
Jun Yan Tai, Kah Hon Leong, Pichiah Saravanan, Sin Tee Tan, Woon Chan Chong, Lan Ching Sim
Summary: This study presents a facile method to prepare carbon quantum dots (CQDs) using human fingernails as a green precursor, which exhibit selective detection of copper ions and enhanced photocatalytic performance for pollutant removal when coupled with g-C3N4. The high loading of CQDs in the composite sensitizes g-C3N4 to sunlight, resulting in improved charge carrier transport and efficient generation of oxidizing radicals for degradation of pollutants.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Applied
Esthela Ramos-Ramirez, Norma Gutierrez-Ortega, Francisco Tzompantzi-Morales, Julio Castillo-Rodriguez, Arturo Barrera-Rodriguez, Gloria Del Angel, Mirella Gutierrez-Arzaluz, Raul Perez-Hernandez, Maria del Pilar Guevara-Hornedo
Summary: In this study, activated Mg/Al layered double hydroxides with layer numbers of 2, 3, and 4 and a mixture of MgO-MgAl2O4 oxides were used as photocatalysts for the degradation of 2,4-dichlorophenol. The results showed that these materials exhibited excellent photocatalytic activity, achieving complete degradation of 2,4-dichlorophenol to mineralization in a short reaction time.
TOPICS IN CATALYSIS
(2022)
Article
Agricultural Engineering
Ning Yan, Meng An, Junyi Chu, Lifeng Cao, Ge Zhu, Weimin Wu, Lu Wang, Yongming Zhang, Bruce E. Rittmann
Summary: The study revealed that a bacterial community acclimated to 4-CP showed improved dechlorination ability, and when mixed with a community acclimated to 2,4-DCP, the removal rate of 2,4-DCP remained high while 4-CP degradation was accelerated. Genera Treponema, Blvii28, Dechloromonas, Nitrospira, and Thauera were found to be more abundant in the 4-CP-dechlorinating biomass, indicating potential roles in 2,4-DCP dechlorination and mineralization.
BIORESOURCE TECHNOLOGY
(2021)
Article
Chemistry, Physical
Lan Ding, Hongjun Zhou, Shouzhen Li, Xiuping Lan, Xinyi Chen, Senwei Zeng
Summary: In this study, conjugated conductive polymer polypyrrole (PPy) molecules were coated on Ag3PO4 nanoparticles to form a core-shell structure (Ag3PO4@PPy). Ag3PO4@PPy exhibited higher photocatalytic activity and stability under visible light compared to pure Ag3PO4. The enhanced stability and activity were attributed to the inhibitory effect of the PPy shell on Ag3PO4 dissolution, increased contact area through the core-shell structure, and the matched energy level structure and outstanding charge transfer ability of PPy that accelerated the photo-generated charge separation.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Environmental Sciences
Yunong Li, Hao Qin, Lixiao Wang, Junhe Lu, Jean-Marc Chovelon, Quansuo Zhou, Yuefei Ji
Summary: This study investigated the photolysis of 2,4-Dichloro-6-nitrophenol (DCNP) in aqueous solutions and found that the anionic form of DCNP is more photoreactive. Several photoproducts were identified, and the primary photochemical mechanisms were discussed. These findings provide insights into the transformation and fate of DCNP in UV-based engineering systems or natural sunlit surface waters.
Article
Materials Science, Multidisciplinary
Sulaiman S. A. Al Ghafry, Mohammed Z. Al-Abri, Basim Al Farsi, Faisal Al Marzouqi, Lamia M. Al Farsi, Nur Adilah Roslan, Azzuliani Supangat
Summary: This study successfully synthesized pristine and gallium doped ZnO nanorods using rapid microwave-assisted method, and investigated the effects of different doping levels. The results showed significant changes in the morphology, crystalline size, and surface roughness of the nanorods with Ga doping. The 1% Ga doping sample exhibited significant enhancement in visible light absorption and rapid degradation.
Article
Chemistry, Physical
Tejaswi Tanaji Salunkhe, Govinda Dharmana, Thirumala Rao Gurugubelli, Babu Bathula, Kisoo Yoo
Summary: Dysprosium-doped ZnO/SnS nanophotocatalysts with different concentrations showed promising photocatalytic activity and suppressed luminescent intensity, indicating potential applications in pollutant degradation.
Article
Environmental Sciences
Xueyu Wei, Xiaofan Yang, Xiaoping Xu, Zhigang Liu, Saraschandra Naraginti, Jie Wan
Summary: A novel magnetically separable stable Ag3PO4/NrGO/CuFe2O4 photocatalyst was developed for efficient detoxification of 2,4-dichlorophenol. This catalyst achieved a 95.3% degradation efficiency in 60 minutes of visible light irradiation, showing high stability and recyclability.
ENVIRONMENTAL RESEARCH
(2021)
Article
Chemistry, Inorganic & Nuclear
Isaias Limon-Rocha, Adriana Marizcal-Barba, C. A. Guzman-Gonzalez, Luis M. Anaya-Esparza, Suresh Ghotekar, O. A. Gonzalez-Vargas, A. Perez-Larios
Summary: In this study, pure TiO2 was synthesized using the sol-gel method and subsequently deposited with metal ions using the deposition-precipitation method. The nanomaterials were characterized and analyzed, and it was found that the Ni/TiO2 nanomaterial showed the best photocatalytic activity in the degradation and mineralization of pollutants.
Article
Materials Science, Ceramics
Ahmed Fattah Abdulrahman, Amad Nori Abdulqodus, Munirah Abdullah Almessiere
Summary: Al-doped ZnO nanoparticles were synthesized using the green method and their dye degradation activity was studied. The results showed that Al-doped ZnO nanoparticles exhibited higher efficiency in degrading dyes compared to pure ZnO nanoparticles.
CERAMICS INTERNATIONAL
(2023)
Article
Environmental Sciences
Jie Li, Yi Li, Haisuo Wu, Saraschandra Naraginti, Pengli Chen, Yang Chen
Summary: The construction of BiOCl/rGO/Ag3PO4 heterojunction was shown to enhance the degradation efficiency of 2,4-dichlorophenol. The degradation efficiency was significantly higher compared to pure Ag3PO4 and pure BiOCl. The degradation mechanism was explained through the principle of heterojunction energy-band theory, and the degradation pathway was analyzed by identifying the degradation products and assessing the phytotoxicity.
Article
Materials Science, Multidisciplinary
Khadijah S. Al-Namshah, Sivalingam Muthu Mariappan, Mohd Shkir, Mohamed S. Hamdy
Summary: In this study, the photocatalytic activity of Ce:ZnO nanocrystals towards the degradation of methyl green dye molecules under black light irradiation was investigated. Ce:ZnO samples were prepared by a simple one-pot method with different Ce concentrations, and their crystal parameters and band gap changes were analyzed. The morphology and composition of Ce:ZnO nanocrystals were studied using scanning electron microscopy and energy dispersive X-ray techniques. Comparisons of the photocatalytic performances between pure ZnO, Ce:ZnO, and CeO2-ZnO composites were made, showing significant improvements in degradation efficiency with the addition of Ce.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
Sulaiman S. A. Al Ghafry, Hamood Al Shidhani, Basim Al Farsi, R. G. Sumesh Sofin, Abdullah S. Al-Hosni, Zahra Alsharji, Jamal Al-Sabahi, Mohammed Z. Al-Abri
Summary: The contamination of water resources is a major environmental concern, especially the presence of hazardous pollutants such as phenol. Therefore, developing cost-effective techniques to remove phenol from water is crucial. This study investigated the use of silver-doped zinc oxide nanorods (Ag-ZnO NRs) for the degradation of phenol under sunlight. The synthesized Ag-ZnO NRs exhibited two distinct structures, hexagonal and cubic, and their optical properties showed significant improvement due to silver doping. The 0.5% Ag-doped ZnO NRs showed the highest photocatalytic activity, achieving a degradation rate of 98.5% for phenol removal under solar light irradiation after 5 hours.
Article
Environmental Sciences
S. Anthonysamy, P. Lahijani, M. Mohammadi, A. R. Mohamed
Summary: This study investigated the low-temperature oxidative uptake of NO on alkali-modified biochar, showing that the NO capture capacity was significantly improved after modification. The adsorption capacity of KOH-activated biochar reached 87.0 mg/g at 30 degrees C, mainly attributed to factors like oxygen functionalities and carbon defects.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2022)
Article
Environmental Sciences
Sze-Mun Lam, Jin-Chung Sin, Honghu Zeng, Hua Lin, Haixiang Li, Abdul Rahman Mohamed, Jun Wei Lim
Summary: A BiFeO3/ZnO composite photocatalyst was successfully fabricated and used in a microbial fuel cell for the first time, achieving simultaneous reduction of Cu2+ ions and power generation. The 3 wt% BiFeO3/ZnO MFC showed the best performance with the maximum power density and Cu2+ removal efficiency, demonstrating good stability and reusability.
Review
Engineering, Environmental
Chin Seng Liew, Normawati M. Yunus, Boredi Silas Chidi, Man Kee Lam, Pei Sean Goh, Mardawani Mohamad, Jin Chung Sin, Sze Mun Lam, Jun Wei Lim, Su Shiung Lam
Summary: Low-cost methods such as vermicomposting and black soldier fly larvae (BSFL) have shown comparable performances to anaerobic digestion in terms of carbon recovery, nitrogen recovery, and mass reduction. However, anaerobic digestion excels in pathogen destruction due to its high operational temperature.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Environmental Sciences
Norhusna Mohamad Nor, Lau Lee Chung, Abdul Rahman Mohamed
Summary: The utilization of microwave heating and nitrogen-modification can generate adsorbents with superior performance for efficient removal of hydrogen sulfide (H2S). The modified palm shell activated carbon synthesized using microwave heating exhibited excellent properties, including a large surface area and new pore structures. Microwave heating assisted in the development of the adsorbent's properties and contributed to high removal of H2S at low adsorption temperature.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Engineering, Environmental
Zeeshan Haider Jaffari, Ather Abbas, Sze-Mun Lam, Sanghun Park, Kangmin Chon, Eun-Sik Kim, Kyung Hwa Cho
Summary: This study focuses on the potential capability of numerous machine learning models to predict the photocatalytic degradation of malachite green. The CatBoost model outperformed others and showed that the photocatalytic reaction conditions were more important than the material properties.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Jin-Han Tan, Jin-Chung Sin, Sze-Mun Lam, Hua Lin, Haixiang Li, Liangliang Huang, Abdul Rahman Mohamed
Summary: Organic pollution and biological hazards have become significant environmental issues. Semiconductor-based photocatalysis is a promising solution to minimize their negative impacts. In this study, novel Z-scheme BaFe2O4/BiOCl nanocomposites were fabricated as efficient visible light-driven photocatalysts. The nanocomposites showed improved photocatalytic activity due to the formation of a Z-scheme heterojunction, leading to enhanced charge transfer and active radical generation. The nanocomposites also exhibited good recyclability and the ability to degrade various organics and inactivate bacteria from wastewater.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Review
Chemistry, Inorganic & Nuclear
Bashaer Mahmoud Namoos, Abdul Rahman Mohamed, Khozema Ahmed Ali
Summary: The desire to improve photocatalytic activity is increasing, especially in semiconductors. Porous photocatalysts have been synthesized to improve surface area and reduce recombination of electron-hole pairs. This paper reviews recent works on porous photocatalysts, with a focus on synthesis and fabrication methods. The topotactic transition technique is the best method for metal oxide porous photocatalysts, while self-organizing blocks are the best method for polymeric porous photocatalysts, especially for growing and fixing 1D semiconductor nanomaterials on 3D and 2D semiconductors on 2D. The hard template method allows for better control of particle shape and size, but the template removal is non-ecofriendly, making the soft template method more favorable. The etching method, on the other hand, is suitable for fabricating porous photocatalysts through a membrane by utilizing the electrical charge created by moving electrons in the electrolyte as a driving force.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Energy & Fuels
Khairun Nadia Muhamad, Nurul Tasnim Sahrin, Raid Abdulrahman Alakeel, Rabbani Syed, Fatima Musa Ardo, Jia Min Woon, Wen Nee Tan, Chin Kui Cheng, Zakariyya Uba Zango, Chii-Dong Ho, Sze Mun Lam, Jin Chung Sin, Kuan Shiong Khoo, Worapon Kiatkittipong, Jun Wei Lim
Summary: The production of hydrogen from microalgae using palm kernel expeller (PKE) as feedstock was studied. A low thermal pre-treatment method using hydrolysis process was used to improve the hydrogen yield. The results showed that the maximum hydrogen yield was achieved using PKE pre-treated at 90 degrees C for 4 h, with a two-fold increase compared to untreated PKE. The release of inhibitory compounds increased significantly at 50 degrees C, and the kinetics of microalgal hydrogen production followed a zeroth order model.
Review
Engineering, Environmental
Michelle Mei Xue Lum, Kim Hoong Ng, Sin Yuan Lai, Abdul Rahman Mohamed, Abdulkareem Ghassan Alsultan, Yun Hin Taufiq-Yap, Mei Kee Koh, Mohamad Azuwa Mohamed, Dai-Viet N. Vo, Manjulla Subramaniam, Kyle Sebastian Mulya, Nathasya Imanuella
Summary: Air pollution from untreated sulfur dioxide-rich flue gas is a major environmental and human health issue. Many sulfur dioxide removal technologies have been developed, but conventional methods generate by-products. Catalytic reduction of sulfur dioxide offers a sustainable solution with high efficiency and the recovery of valuable solid sulfur. This review discusses recent advances and the potential of this technology.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2023)
Article
Environmental Sciences
Chun-Ting Joyee Yap, Sze-Mun Lam, Jin-Chung Sin, Honghu Zeng, Haixiang Li, Liangliang Huang, Hua Lin
Summary: Due to the high pollution of palm oil mill effluent (POME) generated as a result of the prosperous production growth of palm oil in Malaysia, there is an increasing concern for environmental conservation. To address this issue, a cutting-edge photocatalytic fuel cell (PFC) system incorporating ZnO/Zn nanorod array (NRA) photoanode, CuO/Cu cathode, and persulfate (PS) oxidant was successfully designed for the treatment of POME and simultaneous energy production. The PFC/PS system exhibited exceptional performance, achieving high COD removal efficiency, open circuit voltage, short circuit current density, and power density under optimal conditions. The stability, durability, and economic viability of the PFC system were also confirmed through recycling tests and electrical energy efficiency assessment. These findings contribute to enhancing the sustainability and economic viability of palm oil production.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Review
Chemistry, Multidisciplinary
Xin-Quan Tan, Wuwei Mo, Xinlong Lin, Jian Yiing Loh, Abdul Rahman Mohamed, Wee-Jun Ong
Summary: The electro/photocatalytic CO2 reduction reaction (CO2RR) is an important approach for the synthesis of renewable fuels and value-added chemicals. MXenes, a type of 2D transition metal carbides, nitrides, and carbonitrides, show great potential in electrocatalysis and photocatalysis due to their unique properties. This review provides an overview of recent advances in MXene-based catalysts for the electrocatalytic and photocatalytic CO2RR, including their structure, synthesis pathways, and activity enhancement strategies. The review also discusses the current state of research in the field and proposes future perspectives.
Article
Engineering, Environmental
Maher T. Alshamkhani, Lutfi Kurnianditia Putri, Pooya Lahijani, Keat Teong Lee, Abdul Rahman Mohamed
Summary: In this study, an electrochemically exfoliated graphene/graphite carbon nitride ((EG)/g-C3N4) heterojunction photocatalyst was synthesized for CO2 photoreduction to methane. The best-performing photocatalyst (0.075 EG-CN) showed a significant enhancement in CH4 production with 98.6% selectivity after 6 hours of light irradiation compared to pure CN. The developed photocatalyst exhibited high stability after consecutive cycles of CO2 photoreduction to CH4.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Chemistry, Physical
Xin-Quan Tan, Sue-Faye Ng, Abdul Rahman Mohamed, Wee-Jun Ong
Summary: This article introduces the recent advances in experimental and computational studies on the interfacial design of 0D nanostructures on 2D graphitic carbon nitride (g-C3N4). By engineering point-to-face contact between 2D g-C3N4 and 0D nanomaterials, heterojunction interfaces can be formed, which is beneficial for photocatalytic reactions. Different types of 0D nanostructures and synthesis strategies for photocatalytic applications are discussed.
Article
Engineering, Environmental
Noor Izzati Md Rosli, Sze-Mun Lam, Jin-Chung Sin, Lutfi Kurnianditia Putri, Abdul Rahman Mohamed
Summary: In this study, a comparative investigation on the heterojunction formation between g-C3N4 and Ag-based metal oxides (Ag4V2O7, AgFeO2 and Ag2Mo2O7) catalysts was conducted for the degradation of RB5. The g-C3N4/Ag2Mo2O7 catalyst exhibited the highest photocatalytic activity and demonstrated improved optical properties, charge carrier separation and charge transport. The photocatalytic degradation of RB5 followed the trend: g-C3N4/Ag2Mo2O7 > g-C3N4/Ag4V2O7 > g-C3N4/AgFeO2 > g-C3N4. The g-C3N4/Ag2Mo2O7 catalyst also showed promising reusability without significant loss of photoactivity.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Jie-Yinn Tang, Chen-Chen Er, Lling-Lling Tan, Yi-Hao Chew, Abdul Rahman Mohamed, Siang-Piao Chai
Summary: This study systematically unraveled the effect of defect engineering on the properties and catalytic performance of graphitic carbon nitride (g-C3N4). By introducing various defect sites, the study achieved improved charge separation efficiency and CO2 adsorption affinity in g-C3N, providing a more feasible pathway for CO2 reduction.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Panpan Zhang, Xu Wang, Yangyang Yang, Haifeng Yang, Chunsheng Lu, Mingru Su, Yu Zhou, Aichun Dou, Xiaowei Li, Xiaochuan Hou, Yunjian Liu
Summary: In this study, the influence of transition metal doping on the electronic and mechanical properties and electrochemical performance of 2HMoS2/NC was investigated using Cobalt (Co) as an example. Co doping was found to effectively improve the electronic conductivity and active site areas of 2H-MoS2/NC at different positions, optimizing the adsorption and diffusion capability of potassium ions. Furthermore, the study revealed the optimal roles of different types of nitrogen atoms in kinetic adsorption, diffusion, and interfacial stability of potassium ions. These findings provide guidance for the experimental design of high rate 2H-MoS2/NC electrode materials and the optimal design of other functional composite materials.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zeeshan Ajmal, Mahmood Ul Haq, Shahid Zaman, M. K. Al-Muhanna, Anuj Kumar, Mohammed M. Fadhali, Siwar Ben Hadj Hassine, Muhammas Qasim, K. F. Alshammari, Ghulam Abbas Ashraf, Abdul Qadeer, Adil Murtaza, Sulaiman Al-Sulaimi, Huaqiang Zeng
Summary: This study presents a novel heterojunction structure (SrTiO3/CN-TAL10.0) for enhanced photocatalytic water splitting (PWS). The incorporation of thiophenedicarboxaldehyde (TAL) through copolymerization significantly improves the photocatalytic activity of carbon nitride (CN) while maintaining its photostability performance. The optimized composition allows efficient isolation of photoinduced charge carriers and enhanced charge transport, resulting in a remarkable increase in overall photocatalytic efficiency.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Angela Arnosa-Prieto, Patricia Diaz-Rodriguez, Manuel A. Gonzalez-Gomez, Pelayo Garcia-Acevedo, Lisandra de Castro-Alves, Yolanda Pineiro, Jose Rivas
Summary: Macrophages can exhibit different phenotypes depending on the microenvironment and the characteristics of magnetic iron oxide nanoparticles (MNPs). This study demonstrates that the concentration and morphology of MNPs can influence the polarization of macrophages. The findings have implications for therapeutics targeting tissue regeneration and tumor progression.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yu Fang, Cheng-Ye Zhu, Hao-Cheng Yang, Chao Zhang, Zhi-Kang Xu
Summary: This study demonstrates the advantages of vacuum-assisted interfacial polymerization (VAIP) in fabricating polyimide nanofiltration membranes. By using vacuum filtration, aqueous solutions of PIP can be evenly distributed on different microfiltration substrates, leading to the fabrication of uniform and ultra-thin polyamide layers with excellent performance. The membranes exhibit high rejection rates and water permeance, as well as satisfactory long-term stability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R. J. Nelson, Stuart W. Prescott
Summary: Understanding the interactions between polymers and surfactants is crucial for optimizing commercial systems. This study tested the behavior of polymer-surfactant systems, revealing that they do not behave like polyelectrolytes in the presence of salt. Additionally, the structure of polymer-surfactant complexes under confinement differs from that of polyelectrolytes.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yunxiao Xie, Cui Liu, Jie Zhang, Yan Li, Bin Li, Shilin Liu
Summary: This study aimed to improve the microstructure and rheological properties of W/W Pickering emulsions by crosslinking sodium alginate at the water-water interface, thereby enhancing the activity of encapsulated probiotics in simulated gastrointestinal digestion.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Sang Ho Lee, Yige Sun, Patrick S. Grant
Summary: This research developed an effective approach to enhance the charging rates of lithium ion batteries (LIBs) by strategically incorporating carbon nanotube (CNT) conductivity boosters into Li4Ti5O12 (LTO) electrodes. Multi-layer architectures comprising CNT-rich and CNT-free LTO electrode layers were manufactured using a layer-by-layer spray coating method to promote charge transfer kinetics of high mass loading electrodes. The best performing multi-layer was paired with a spray-coated LiFePO4 (LFP) positive electrode, resulting in attractive power performance that outperformed conventional LTO || LFP combinations.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jingwei Liang, Shaobin Li, Fengbo Li, Li Zhang, Yufeng Jiang, Huiyuan Ma, Kun Cheng, Liang Qing
Summary: A molybdenum-regulated self-supporting electrode material with rich vacancy defects has been successfully synthesized and shows exceptional catalytic activities and stability for electrocatalytic overall water splitting. This study provides a new perspective for the design and synthesis of non-precious metal bifunctional electrocatalysts.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jonas Blahnik, Jennifer Schuster, Rainer Mueller, Eva Mueller, Werner Kunz
Summary: This study investigates the relationship between the morphology of PMMA monopolymers and PMMA-PHEMA copolymers with the expected nature of surfactant-free microemulsions (SFMEs) before polymerization. It is found that previously mesostructured, surfactant-free mixtures can produce porous polymers of different morphologies, while unstructured, oil-rich regions lead to solid, transparent polymers without nanostructured morphologies. Additionally, a surfactant-based reference system shows similar phase behavior and polymer morphologies as the comparable surfactant-free system, indicating the importance of the hydrotropic behavior of HEMA in this system.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zheng-Fen Pu, Wen-Zhi She, Rong Sheng Li, Qiu-Lin Wen, Bi-Chao Wu, Chun-Hua Li, Jian Ling, Qiue Cao
Summary: This study synthesized two framework-isomeric covalent organic frameworks (COFs) and discovered that the light scattering signal of COFs can be used for the analytical detection of lead ions. By controlling synthesis conditions and introducing regulators, the morphology of COFs could be controlled and framework-isomeric COFs could be precisely synthesized.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yuchen Weng, Ying Hong, Jingyu Deng, Sicheng Cao, Li-Juan Fan
Summary: This paper reports the preparation of dynamic color-changing fluorescent polymer nanoparticles (PNPs) by constructing a fluorescence resonance energy transfer (FRET) pair. The PNPs show excellent anti-counterfeiting effects and reproducibility. The study demonstrates a promising encryption strategy that can achieve multiple outputs with simple operation.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Guodong Liu, Zijian Wang, Jianing Wang, Hanbin Liu, Zhijian Li
Summary: This study investigates the combination of multicolor switchable polyaniline (PANI) electrode and 1-methyl-4,4'-bipyridyl iodide (MBI), which demonstrates superior optical properties in visible and near-infrared light modulation, as well as excellent electrochemical performances. This combination can be used to develop novel electrochromic devices for applications in smart packaging, smart labels, and flexible smart windows.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Huying Yan, Yang Guo, Xingzhi Bai, Jiawei Qi, Haipeng Lu
Summary: By modifying Ti3C2Tx through heterogeneous interface engineering, optimized impedance matching is achieved, leading to enhanced electromagnetic wave absorption performance.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Kehu Zhang, Yang Zhou, Silvia Moreno, Simona Schwarz, Susanne Boye, Brigitte Voit, Dietmar Appelhans
Summary: This article presents an advanced crosslinking strategy to fabricate clustered polymersomes using host-guest interactions. By controlling the input of crosslinker and environmental conditions, reversible aggregation and disassembly of these polymersomes can be achieved. The size and structure of these clustered polymersomes can be regulated and visualized through a fluorescent enzymatic cascade reaction.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Junjie Xu, Weixiong Huang, Ruiling Li, Li Li, Jinjin Ma, Jiaou Qi, Haiyan Ma, Min Ruan, Lilin Lu
Summary: In this study, a potassium doped palladium catalyst was developed for acetylene hydrogenation, showing excellent catalytic performance and durability. The doping of potassium effectively weakened the adsorption of ethylene, improved ethylene selectivity, and lowered the barriers of hydrogen activation and transfer reactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
