4.7 Article

Microstructures, surface states and field emission mechanism of graphene-tin/tin oxide hybrids

期刊

JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 395, 期 -, 页码 40-44

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2012.11.006

关键词

Graphene-Sn/SnO2 hybrids; Microstructures; Surface state; Field emission mechanism

资金

  1. Natural Science Foundation of China [91123019, 61176056]
  2. 13115 Innovation Engineering of Shaanxi Province [2010ZDKG-58]
  3. Institute of Photonics and Photo-Technology, Provincial Key Laboratory of Photoelectronic Technology, Northwest University, China

向作者/读者索取更多资源

The effects of microstructures and surface states on the field emission, which are important to a good understanding of the field emission mechanism, are unclear. In this paper, the microstructures and surface states of graphene-Sn/SnO2 hybrids were analyzed, and the field emission mechanism was explored. Raman spectra and images revealed that SnO2/Sn droplets are strongly bound on graphene surface, and there exist oxygen vacancies at the surface of graphene-Sn/SnO2 hybrids. Among X-ray photoelectron spectroscopy spectra, the peak of 0 15 shifts 1.6 eV toward higher binding energies in the 5 min sample with the best field emission properties, which indicates that the field emission improvement in graphene-Sn/SnO2 hybrids arises from the band-bending effect and a lower work function. Crown Copyright (C) 2012 Published by Elsevier Inc. All rights reserved.

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