期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 357, 期 1, 页码 252-254出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2011.01.083
关键词
Magnetic materials; Ferrotluid; Ionic liquid; Nanoparticle; Viscoelasticity
资金
- Junta de Andalucia, Spain [P08-FQM-3993, P09-FQM-4787]
- MICINN, Spain [FIS2009-07321]
- University of Granada (Spain)
With this work we would like to emphasize the necessity of steric repulsion to stabilize novel ionic liquid-based ferrofluids. For this purpose, we prepared a suspension of magnetite nanoparticles coated with a double layer of oleic acid, dispersed in 1-ethyl-3-methylimidazolium ethylsulphate ([EMIM][EtSO4]). For comparison, a suspension of bare magnetite nanoparticles in [EMIM][EtSO4] was also prepared. The stability of these suspensions was checked by magnetic sedimentation and centrifugation processes. Furthermore, their yield stress was measured as a function of the applied magnetic field, which gave additional information on their stability. The results of these experiments showed that the suspension of bare nanoparticles was rather unstable, whereas the suspension of double layer coated nanoparticles gave rise to a true (stable) ferrofluid. (C) 2011 Elsevier Inc. All rights reserved.
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