期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 318, 期 2, 页码 167-174出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2007.10.045
关键词
petroleum resins; adsorption; near infrared (NIR) spectroscopy; partial least squares (PLS) regression; quartz sand; Langmuir model
In this paper we have tried to evaluate adsorption parameters of petroleum resins. Near infrared (NIR) spectroscopy is applied for resins bulk concentration evaluation during adsorption process. NIR experimental scheme and parameters are provided. NIR spectra range of 900013,000 cm(-1) is chosen. Quartz sand (0.2-0.8 rum fraction) is used as adsorbent; benzene is used as solvent. Different approaches of NIR spectra-resins concentration calibration model building are discussed. Partial least squares (PLS) regression method is used. Langmuir model is chosen for experimental data fitting. Combined usage of kinetic and isothermic data gives us ability to evaluate the maximal adsorbed mass density, the equilibrium constant of adsorption, and the rate constants of adsorption (and desorption). The rate constants of resins adsorption and desorption are found to be concentration independent. (c) 2007 Elsevier Inc. All rights reserved.
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