期刊
JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH
卷 8, 期 3, 页码 401-407出版社
SPRINGER
DOI: 10.1007/s11998-010-9308-8
关键词
Core-shell; Fluorine-containing; Styrene-acrylate latex; Reactive surfactant
资金
- Science and Technology Planning Project of Guangdong Province, China [2009B011000010]
- Fundamental Funds for the Central Universities [2009ZM0288]
Fluorine-containing poly-styrene-acrylate (PSA) latex with core-shell structure was successfully synthesized by seeded semicontinuous emulsion polymerization using fluorine monomer Actyflon-G(04) and reactive emulsifier DNS-86. The chemical composition, morphology of latex, and surface composition of the latex film were characterized by Fourier transform infrared spectra, transmission electron microscopy, and X-ray photoelectron spectroscopy, respectively. The stability properties of latex were tested by Ca(2+), centrifugal and mechanical stability tests, and the latex film was studied by water contact angle, water absorption ratio, and thermo-gravimetric analysis. The results show that fluorine-containing PSA latex particles with crosslinked core and crosslinked shell structure have excellent stability properties, and the film of latex has excellent water repellency, thermal stability, and chemical resistance properties when the amount of fluorine monomer was only 8.0 wt%.
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