Gibbs-preserving maps outperform thermal operations in the quantum regime

In this brief paper, we compare two frameworks for characterizing possible operations in quantum thermodynamics. One framework considers thermal operations-unitaries which conserve energy. The other framework considers all maps which preserve the Gibbs state at a given temperature. Thermal operations preserve the Gibbs state; hence a natural question which arises is whether the two frameworks are equivalent. Classically, this is true-Gibbs-preserving maps are no more powerful than thermal operations. Here, we show that this no longer holds in the quantum regime: a Gibbs-preserving map can generate coherent superpositions of energy levels while thermal operations cannot. This gap has an impact on clarifying a mathematical framework for quantum thermodynamics.