期刊
NEW JOURNAL OF CHEMISTRY
卷 39, 期 5, 页码 3424-3434出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj00330j
关键词
-
资金
- Foundation of Science and Technology (FCT), Portugal [SFRH/BPD/78264/2011, SFRH/BPD/76192/2011, UID/QUI/00100/2013]
- [Slovakia: VEGA 1/0233/12]
- [APVV-0014-11]
The syntheses and X-ray diffraction structures of water soluble copper(II) compounds containing the Schiff base ligand 2-(2-pyridylmethyleneamino) benzenesulfonate (L-), viz. the dinuclear bis-mu(1,1)-azido [CuL(mu(1,1)-N-3)](2) (1) and bis-mu(1,3)-thiocyanato [CuL(mu(1,3)-NCS)](2)center dot 2H(2)O (2) complexes and the mu(1,5)-dicyanamide coordination polymer [CuL(mu(1,5)-NCNCN)](n)center dot nH(2)O (3), are reported. The one dimensional chain in 3 propagated through mu(1,5)-dicyanamide bridges is stabilized by a new type of sixteen membered metalla-cycle supported by copper and H-bonds. Variable-temperature (2-300 K) magnetic studies indicate that there is a weak ferromagnetic exchange coupling in 1, while 2 and 3 have weak antiferromagnetic exchange interactions. They catalyze the diastereoselective nitroaldol (Henry) reaction of different aldehydes with nitroethane in aqueous medium. Water was the solvent used for both the syntheses and catalytic studies.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据