Article
Engineering, Electrical & Electronic
Muhammad Abdul Basit, Faizan Raza, Gohar Ali, Amna Parveen, Mahmood Khan, Tae Joo Park
Summary: This study demonstrates the generation of visible light photocatalytic and photothermal activity in carbon fibers network by depositing TiO2-CdS nanocomposite. The combination of CdS QDs-sensitized TiO2 nanocomposites and CFs shows potential for simultaneous photocatalytic and photothermal water purification, which can be further optimized and extended.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2022)
Article
Chemistry, Physical
Jiangpeng Wang, Yaoxun Fang, Wenxuan Zhang, Xuelian Yu, Lin Wang, Yihe Zhang
Summary: The TiO2/BiOBr 2D-2D heterojunction photocatalysts showed excellent photocatalytic nitrogen fixation activity with a maximum NH3 production rate of 1.43 mmol/g/h for the 15% TiO2/BiOBr catalyst, which was about 4 times higher than that of pure BiOBr. The enhanced performance can be attributed to the 2D interface between TiO2 and BiOBr nanosheets, which facilitates the transfer of photogenerated electrons and increases electron participation in the nitrogen fixation reaction. This study highlights the potential of 2D-2D heterojunctions as an effective strategy to enhance solar energy utilization.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Marziye Modares, Somayeh Alijani, Bahram Nasernejad
Summary: ZnO-CdS composites with different loadings of CdS were synthesized for NOx degradation under visible light. The presence of CdS influenced the morphology and structure of the composites, leading to the formation of needle/flower-like structures. The composites with CdS showed increased surface area and enhanced visible light absorption. Compared to pristine ZnO, the photocatalytic activity of ZnO-CdS composites was higher, with the optimal CdS loading being 15%. The formation of heterojunction structure between CdS and ZnO was responsible for the high photocatalytic performance of the composites.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Environmental Sciences
Khaled Benabbas, Nassira Zabat, Imene Hocini
Summary: A Fe3O4/CuO core-shell heterostructure photocatalyst was successfully synthesized via hydrothermal method, exhibiting excellent photodegradation activity for azo dye Direct Red 89 under visible light irradiation. The catalyst showed enhanced photocatalytic performance compared to pure Fe(3)O(4)or CuO, and maintained high activity even at high dye concentrations. Additionally, the catalyst's paramagnetic property facilitated its recovery and reuse.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Materials Science, Multidisciplinary
Gedeng Wan, Yongqiang Yang, Huaze Zhu, Chao Zhen, Xiaoxiang Xu, Lianzhou Wang, Gang Liu
Summary: This study demonstrates the fast migration and efficient spatial separation of photogenerated charges in photocatalytic materials by constructing a three-phase heterostructure of CdS/PbTiO3/TiO2, leading to improved efficiency in solar water splitting reactions.
SCIENCE CHINA-MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Yarabahally R. Girish, Udayabhanu, Gubran Alnaggar, Abdo Hezam, Mysore B. Nayan, Ganganagappa Nagaraju, Kullaiah Byrappa
Summary: TiO2 was successfully coupled with g-C3N4 to create an advanced heterojunction photocatalyst. The prepared nanocomposite showed significantly enhanced photocatalytic efficiency in hydrogen production and dye degradation. The interfacial contact between TiO2 and g-C3N4 effectively reduced electron hole recombination, resulting in improved photocatalytic activity.
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES
(2022)
Article
Engineering, Environmental
Marica Muscetta, Samar Al Jitan, Giovanni Palmisano, Roberto Andreozzi, Raffaele Marotta, Stefano Cimino, Ilaria Di Somma
Summary: A visible light-driven photocatalytic hydrogen production system using a Cu2O/TiO2 composite material was evaluated. A simple ball-milling method was proposed for preparing the Cu2O/TiO2 photocatalyst, and the effects of Cu2O loading and operating conditions were analyzed. The results indicated that the optimized composite catalyst achieved high hydrogen production and light to chemical conversion under visible light conditions.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Dingyu Li, Chengwu Yang, Saravanan Rajendran, Jiaqian Qin, Xinyu Zhang
Summary: In this study, a highly efficient Ti3CN@TiO2/CdS photocatalyst was reported. Ti3CN@TiO2 materials with different morphologies were obtained from Ti3AlCN by controlling the etching time, and CdS nanoparticles were loaded onto the catalyst to improve its photocatalytic efficiency.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Perumal Devaraji, Ruchao Gao, Liuying Xiong, Xinjia Jia, Li Huang, Wei Chen, Shanhu Liu, Liqun Mao
Summary: This study reports for the first time an efficient black TiO2/CdS hetero-structure with high photocatalytic hydrogen generation activity. The sheet like leaf structure of LBT/CdS exhibits a higher rate of H2 production, attributed to the hetero-junction between the two materials and the introduction of black leaf-TiO2 which enhances charge carrier mobility.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Nanoscience & Nanotechnology
Chuanqi Pan, Huan Shen, Guoli Liu, Xiang Zhang, Xiaoxuan Liu, Huifeng Liu, Peiyan Xu, Wei Chen, Yuan Tian, Hongtao Deng, Hongwei Sun, Jinlong Wang, Zhu Luo, Lizhi Zhang, Yanbing Guo
Summary: Bacterial infections can lead to deadly diseases, but CuO/TiO2 nanobelts with surface oxygen vacancies (Ov) show excellent antibacterial properties. The addition of Ov significantly enhances the photocatalytic inactivation performance of the nanobelts.
ACS APPLIED NANO MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Yong Li, Yanfang Liu, Mingqing Zhang, Qianyu Zhou, Xin Li, Tianlu Chen, Shifeng Wang
Summary: This study successfully prepared Ag3PO4/TiO2(B) heterojunction composite photocatalyst using the abundant solar energy resources in Tibet. By constructing heterojunctions, the light absorption range of the photocatalyst was extended, inhibiting the recombination of photogenerated electron-hole pairs and greatly enhancing its light quantum efficiency.
Article
Materials Science, Multidisciplinary
O. Mertah, K. El Hajjaji, S. El Amrani, K. Tanji, I. Goncharova, A. Kherbeche
Summary: The heterostructures of Cu/TiO2@Ag3PO4, formed by placing Cu/TiO2 nanoparticles on Ag3PO4, can significantly enhance the photocatalytic activity for nitrate reduction under simulated visible light irradiation and exhibit good antibacterial activities against E. coli and S. aureus.
Article
Chemistry, Physical
He Jiang, Yan Zhong, Kaixun Tian, Haoliang Pang, Yaoyao Hao
Summary: The study demonstrates the successful degradation of bisphenol A (BPA) using a nitrogen- and sulfur-doped carbon quantum dot-modified MIL-101(Fe) heterojunction under visible light-induced activation of persulfate. The composite material shows remarkable catalytic performance and excellent reusability, providing a novel perspective on the fabrication of heterojunction photocatalysts for organic contaminant degradation.
APPLIED SURFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Kamol Dey, Sonalika Vaidya, Anna Gobetti, Giorgio Ramorino, Ashok K. Ganguli
Summary: Undoped and N-doped TiO2 anatase/brookite mixed-phase nanoparticles were synthesized via a sol-gel method using urea as a nitrogen source. Nitrogen played a dual role in doping and controlling the anatase and brookite phases in the nanoparticles. N-doped anatase/brookite mixed-phase nanoparticles exhibited superior photocatalytic activity in degrading rhodamine-B under simulated visible light irradiation.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Yifan Wang, Xiangyu Meng, Qiyu Hu, Meiyu Zhang, Xiaohu Cao, Chunjiang Xu, Yong Ding
Summary: The combination of Ti3+ doped TiO2-x with ZnIn2S4 resulted in a novel photocatalyst with improved hydrogen evolution reaction (HER) performance compared to TiO2-x alone. The formation of a Type II heterojunction enhanced the separation of photogenerated carriers and electron transfer rate, leading to higher hydrogen evolution rate.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Immunology
Jie Song, Aole Li, Yu Qian, Bin Liu, Linshuoshuo Lv, Ding Ye, Xiaohui Sun, Yingying Mao
Summary: This study systematically evaluated the role of circulating cytokines on the risk of cancer using a genetic epidemiological approach. The results showed that genetically predicted high levels of interleukin-18 were associated with a decreased risk of acute myeloid leukemia, and circulating levels of IL-17 were associated with altered stomach cancer risk. Additionally, suggestive evidence for other cytokine-cancer associations was found.
FRONTIERS IN IMMUNOLOGY
(2022)
Article
Chemistry, Physical
Huinan Che, Peifang Wang, Juan Chen, Xin Gao, Bin Liu, Yanhui Ao
Summary: This study successfully improved the activation ability of PDS by synthesizing a novel PCN/4-MI D-A conjugated polymer, providing a new design concept for highly efficient PDS activation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Physical
Yuanhao Cheng, Juan Chen, Peifang Wang, Wei Liu, Huinan Che, Xin Gao, Bin Liu, Yanhui Ao
Summary: In this work, a Z-scheme Bi2S3-Bi2WO6 heterojunction with interfacial Bi-S bonds was constructed. The obtained BS-BWO heterojunction exhibited significantly enhanced piezocatalytic performance, which could be attributed to the Z-scheme charge transfer through the formed Bi-S bonds. The increased piezoelectric potential of BS-BWO also contributed to the enhanced piezocatalytic performance, as supported by COMSOL simulation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Review
Chemistry, Multidisciplinary
Junming Zhang, Hong Bin Yang, Daojin Zhou, Bin Liu
Summary: This review provides a comprehensive introduction to the importance of adsorption energy in electrochemical reactions and its role in bridging the gap between catalyst structure and activity. Focusing on oxygen electrocatalysis, it discusses the selection of adsorption energy as an activity descriptor, intrinsic and empirical relationships related to adsorption energy, the link between structure and electrocatalytic performance, approaches to obtain adsorption energy, strategies to improve catalytic activity by modulating adsorption energy, extrinsic influences on adsorption energy from the environment, and methods to bypass linear scaling relations of adsorption energy. An outlook is also provided, highlighting possible future investigations related to the obstacles between adsorption energy and electrocatalytic performance.
Article
Multidisciplinary Sciences
Jiadong Chen, Chunhong Chen, Minkai Qin, Ben Li, Binbin Lin, Qing Mao, Hongbin Yang, Bin Liu, Yong Wang
Summary: In this study, the integration of Ru nanoparticles on oxygen-deficient WO3-x was found to greatly enhance the activity of hydrogen evolution reaction. Oxygen-deficient WO3-x has a large capacity for storing protons, which increases the hydrogen coverage on the surface of Ru nanoparticles.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Yingying Wen, Juan Chen, Xin Gao, Huinan Che, Peifang Wang, Bin Liu, Yanhui Ao
Summary: This study investigates the effect of hydrodynamic factors on the performance of water-driven piezo-enhanced photocatalysis. The results reveal that velocity and the porous structure of the substrate significantly impact the piezo-photocatalytic process, enhancing the catalytic performance. The findings provide a feasible method for in-situ purification of pollutants in urban sewerage and drainage.
Article
Infectious Diseases
Lei Liu, Bin Liu, Liang Li, Ming-Xin He, Xiang-Dong Zhou, Qi Li
Summary: This study found that myrtenol attenuates biofilm formation and virulence of Acinetobacter baumannii through suppressing the expression of related genes and improving the susceptibility to certain antibiotics.
INFECTION AND DRUG RESISTANCE
(2022)
Article
Chemistry, Physical
Ze-Wen Kang, Jun-Yu Zhang, Ze-Zhen Li, Ranjith Kumar Kankala, Shi-Bin Wang, Ai-Zheng Chen
Summary: This study demonstrates a green, efficient, and fast strategy for fabricating high-performance nanozymes through the supercritical CO2 fluid technology. The C-doped Co3O4 nanozyme, prepared by coating poly-(methyl vinyl ether-co-maleic anhydride) (PVM/MA) and calcination, exhibits significant peroxidase-like catalytic activity and glucose sensing performance. The DFT calculations reveal that the doped nano-enzyme catalytic site has a unique electronic structure, improving the enzyme catalytic and sensor performance.
Article
Engineering, Environmental
Bingkun Huang, Xinyi Ren, Jian Zhao, Zelin Wu, Xinhao Wang, Xinyu Song, Xuning Li, Bin Liu, Zhaokun Xiong, Bo Lai
Summary: This study reports the functional group modification of model single atom catalysts (SACs) to improve the catalytic performance in Fenton-like reactions. The modified cobalt phthalocyanine catalyst exhibited superior catalytic activity and the mechanism was revealed through density functional theory (DFT) calculations. Scale-up experiments also demonstrated the stability and efficiency of the catalyst.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Review
Chemistry, Multidisciplinary
Zewen Kang, Junyu Zhang, Xiaohua Guo, Yangfan Mao, Zhimin Yang, Ranjith Kumar Kankala, Peng Zhao, Ai-Zheng Chen
Summary: Metal oxides have attracted significant interest as catalysts in various reactions, and transmission electron microscopy (TEM) has been used to study their morphology, phase, structure, and chemical information. Recent advances in liquid-phase TEM have enabled the real-time imaging of metal oxides in solution, allowing for the characterization of their dynamic structure, morphology, and composition under working conditions. This review introduces the recent progress in liquid cells, specifically closed liquid cell chips, and discusses the advances in particle growth, phase transformation, self-assembly, core-shell nanostructure growth, and chemical etching. The application of liquid-phase TEM in understanding fundamental processes of metal oxides for CO2 reduction and water-splitting reactions is also highlighted, along with the future outlook and challenges in this research field.
Article
Chemistry, Physical
Yinyin Wang, Jiankang Zhao, Cong Cao, Jie Ding, Ruyang Wang, Jie Zeng, Jun Bao, Bin Liu
Summary: Electrosynthesis of valuable chemicals from CO2 or CO offers a promising approach to store renewable electricity and reduce carbon emission. In this study, amino functionalized Cu surface (Cu@NH2) derived from in situ electroreduction of copper ammonia chloride complexes exhibits significant catalytic performance for CO reduction to acetate. The amino groups on the Cu surface play a crucial role in maintaining the low valence state of Cu and stabilizing the oxygen-containing intermediates, thus promoting the coupling reaction between *CO and *CHO to form acetate.
Review
Materials Science, Multidisciplinary
Qiang Zhang, Juan Chen, Huinan Che, Peifang Wang, Bin Liu, Yanhui Ao
Summary: This article reviews the research on photocatalytic hydrogen evolution based on graphitic carbon nitride and introduces the design strategies and mechanisms of donor-acceptor type photocatalysts. The article also provides an overview of the major challenges and opportunities in this research field and shows the implications for future studies.
ACS MATERIALS LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Junming Zhang, Xueli Cao, Ya-Fei Jiang, Sung-Fu Hung, Wei Liu, Hong Bin Yang, Cong-Qiao Xu, Dong-Sheng Li, Tianyu Zhang, Yujing Li, Jun Li, Bin Liu
Summary: Enriching the surface of IrRu alloy with Ir during the oxygen evolution reaction (OER) has been investigated. The in situ enrichment of Ir on the surface of IrRu alloy was characterized by various techniques, and a low Ir content (20 wt%) IrRu alloy was successfully synthesized. The IrRu alloy exhibited excellent catalytic performance and stability, indicating its potential for practical applications in proton exchange membrane (PEM) water electrolyzers.
Article
Chemistry, Physical
Dongmeng Su, Zhenhui Lam, Yonglong Zheng, Yawen Wang, Bin Liu, Hongyu Chen
Summary: Vertical nanowire arrays (NWAs) have attracted significant attention for their excellent electronic and materials transport properties. However, the peel-off of metal NWAs remains a major challenge for their practical applications. In this study, the peel-off problem is investigated and improved synthesis is discussed as a solution. It is found that the robustness of the Au NWAs mainly depends on their surface hydrophilicity. Notably, sulfide treatment of the NH2-functionalized substrate leads to sparser and longer Au NWAs with improved robustness.
Article
Chemistry, Inorganic & Nuclear
Ran Chen, Juan Chen, Huinan Che, Gang Zhou, Yanhui Ao, Bin Liu
Summary: In this study, atomically dispersed main group magnesium (Mg) was introduced onto CdS monodispersed nanospheres, greatly enhancing the photocatalytic hydrogen evolution reaction. The atomically dispersed Mg acts as an electron sink, trapping photogenerated electrons and reducing the Gibbs free energy of hydrogen evolution reaction (HER), leading to accelerated HER and improved efficiency.
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)