期刊
NEW JOURNAL OF CHEMISTRY
卷 39, 期 12, 页码 9729-9734出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj01517k
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资金
- Research Council of the University of Isfahan
A new palladium N-heterocyclic carbene complex using 3,5-di(1H-imidazol-1-yl)pyridine (1) as a precursor was prepared. The complex was immobilized on 3-chloropropylated nanosilica as a support and characterized by FT-IR spectroscopy, thermogravimetric analysis, field emission scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy and elemental analysis. The prepared catalyst was used as a heterogeneous catalyst in the Suzuki-Miyaura coupling reactions of various aryl halides with phenylboronic acid and the corresponding biphenyls were being produced in a high yield. The catalyst was recyclable under aerobic conditions without significant Loss of activity. Aka, the catalytic activity of homogeneous catalyst was investigated.
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