Article
Chemistry, Applied
David Moreno-Gonzalez, Pavel Jac, Petra Riasova, Lucie Novakova
Summary: A simple and sensitive method for determining patulin in apple-based products at low levels has been developed, utilizing molecularly imprinted polymer solid-phase extraction microcartridge in capillary electrophoresis with mass spectrometry. The method showed excellent validation parameters for patulin and successfully analyzed patulin content in various apple-based products, demonstrating high accuracy and precision.
Article
Chemistry, Analytical
Elif Esen, Bilgen Osman, M. Nalan Demir
Summary: MLT-imprinted microbeads were prepared for SPE of MLT from edible plants. The MIP showed high adsorption capacity and selectivity for MLT, leading to efficient extraction from various plant samples for HPLC analysis. The SPE method using MLT-PEMATrp microbeads was highly effective and had a low LOD.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Analytical
Ali Akbar Fathi, Mohammad Reza Afshar Mogaddam, Saeed Mohammad Sorouraddin, Mir Ali Farajzadeh, Ali Mohebbi
Summary: This research aims to synthesize a specific and efficient sorbent for the extraction and determination of apixaban from human plasma samples. The combination of a molecularly imprinted polymer with magnetic metal organic framework nanocomposite provided a highly efficient analytical method. The method showed a wide linear range, low limit of detection, high extraction recovery, and good precision, indicating its high potential for screening apixaban in human plasma samples.
JOURNAL OF SEPARATION SCIENCE
(2023)
Article
Chemistry, Analytical
Abolghasem Jouyban, Mir Ali Farajzadeh, Mohammad Reza Afshar Mogaddam, Mahboob Nemati, Maryam Khoubnasabjafari, Vahid Jouyban-Gharamaleki
Summary: The study presents a solid phase extraction method utilizing a molecularly imprinted polymer and deep eutectic solvents-dispersive liquid-liquid microextraction for the extraction and quantification of valproic acid from exhaled breath condensate samples. The method demonstrated low limits of detection and quantification, good repeatability, accuracy, and stability. It was successfully applied to exhaled breath condensate samples from patients under valproic acid treatment.
MICROCHEMICAL JOURNAL
(2021)
Article
Biophysics
Patrycja Lach, Alvaro Garcia-Cruz, Francesco Canfarotta, Alistair Groves, Jakub Kalecki, Dominik Korol, Pawel Borowicz, Kostiantyn Nikiforow, Maciej Cieplak, Wlodzimierz Kutner, Sergey A. Piletsky, Piyush Sindhu Sharma
Summary: Redox-active MIP-Gly NPs were developed by incorporating ferrocenylmethyl methacrylate into the synthesis process, enabling them to selectively determine glyphosate without the need for redox probe. MIP-Gly NPs synthesized using allylamine and squaramide-based monomers exhibited the highest selectivity. The MIP-Gly NPs modified Pt-SPEs were characterized using differential pulse voltammetry and electrochemical impedance spectroscopy, with changes in the oxidation peak of the ferrocenyl moieties serving as the analytical signal. The chemosensor showed a low limit of detection and a wide linear dynamic concentration range for glyphosate, allowing successful detection in spiked river water samples.
BIOSENSORS & BIOELECTRONICS
(2023)
Article
Chemistry, Analytical
Ahmed Qasim Abdulhussein, Nor Kartini Abu Bakar, Husam I. S. Kafeenah, Arniza Khairani Mohd Jamil
Summary: This study presents the development of a selective and sensitive dual-template molecularly imprinted polymer nanoparticles (MIPs) for simultaneous removal and clean up of nitenpyram (NIT) and imidacloprid (IMI) pesticide residues from honey samples. The determination and quantification of the pesticides were performed using ultra-high-performance liquid chromatography-tandem mass spectrometry. The developed method showed low method limit of detection and limit of quantification, and high precision.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
(2023)
Review
Chemistry, Analytical
Rafael Oliveira Martins, Ricardo Alves Bernardo, Lucas Santos Machado, Almir Custodio Batista Junior, Lanaia Itala Louzeiro Maciel, Deborah Victoria Alves de Aguiar, Flavio Olimpio Sanches Neto, Joao Victor Ataide Oliverira, Rosineide Costa Simas, Andrea Rodrigues Chaves
Summary: Molecularly imprinted polymers (MIPs) have been widely used for complex sample evaluation. However, the use of toxic reagents and solvents in the traditional synthesis methods has raised environmental concerns. Green synthesis strategies and computational modeling have been introduced to address this issue.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Rail Ilktac, Zinar Pinar Gumus
Summary: The study utilized magnetic-molecularly imprinted polymer for the preconcentration of trace levels of imidacloprid in water and apple samples. The developed method showed good selectivity, sensitivity, and resolving power, and can be used for at least ten cycles.
TURKISH JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Analytical
Dominik Korol, Anna Kisiel, Maciej Cieplak, Agata Michalska, Piyush Sindhu Sharma, Krzysztof Maksymiuk
Summary: Electrochemically active molecularly imprinted polypyrrole nanoparticles (PPy NPs) were synthesized using micelles. The NPs with estriol imprinting were prepared by polymerizing pyrrole with the aid of iron(III) p-toluenesulfonate. SEM and TEM confirmed the synthesis of imprinted PPy NPs around 60 nm in size. The NPs prepared with pristine pyrrole showed an imprinting factor of 4.2, while those prepared with derivatized pyrrole showed no imprinting. The electrochemical-based transduction allowed for the determination of estriol in a concentration range of 0.5-5 μM and 10-100 μM, with a limit of detection (LOD) of 0.16 μM. The MIP NP-coated electrode exhibited satisfactory selectivity towards estriol and its structural analogs.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Review
Chemistry, Analytical
Ruoyang Liu, Chi-Chiu Ko
Summary: MIP-based luminescent chemosensors have been widely studied due to their high specificity and sensitivity in molecular recognition and luminescence detection. Different strategies, including incorporation of luminescent functional monomers and surface-imprinting polymerization on luminescent nanomaterials, have been used to construct luminescent MIPs for various analytes. This review discusses the design strategies, sensing approaches, and applications of luminescent MIP-based chemosensors in biosensing, bioimaging, food safety, and clinical diagnosis, as well as the limitations and prospects for future development.
Article
Agriculture, Multidisciplinary
Su Han Wang, Jian Ping Wang, Ning Peng Wu
Summary: In this study, a practical method for detecting sulfonamide residues in pork samples was developed. A magnetic molecularly imprinted polymer was synthesized to recognize 35 sulfonamide species, and a dispersive solid-phase extraction method coupled with ultra-performance liquid chromatography photodiode array method was utilized for extraction and determination. The developed method exhibited high adsorption capacity, recovery, and enrichment factor, with detection limits in the range of 0.08-0.53 ng g(-1). Compared with previous methods, the present method showed better performance in sample preparation and instrumental analysis.
JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE
(2023)
Article
Polymer Science
Guillaume Palaprat, Anne-Francoise Mingotaud, Dominique Langevin, Monique Mauzac, Jean-Daniel Marty
Summary: The study investigated a cholesteric network with two levels of chirality in gas phase towards the sorption properties of two enantiomers of a chiral amine, finding that both levels of chirality improved separation, with the presence of chiral-specific molecular cavities having a greater effect than the chiral environment.
Article
Biochemical Research Methods
Fang-Yi Liao, Jing-Ru Weng, Ying-Chi Lin, Chia-Hsien Feng
Summary: This study developed a D-mu SPE method combining dispersing liquid-liquid extraction and solid-phase extraction for extracting histamine in wine samples. The optimized method showed improved extraction performance and sensitivity, with significantly reduced synthesis time using microwave energy.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Article
Polymer Science
Sarah H. Megahed, Mohammad Abdel-Halim, Amr Hefnawy, Heba Handoussa, Boris Mizaikoff, Nesrine A. El Gohary
Summary: This study used molecularly imprinted polymers (MIPs) for selective extraction of quinic acid (QA) from coffee bean extract. Computational modeling and equilibrium rebinding studies were performed to optimize the preparation of MIP C, which showed better binding performance than other MIPs tested. The applied molecularly imprinted solid-phase extraction (MISPE) using MIP C was able to selectively extract QA from aqueous coffee extract, with reduced interference from other components.
Article
Chemistry, Analytical
Jialing Zhao, Hui He, Zhanchen Guo, Zhen Liu
Summary: Phosphorylation is a common post-translational modification in mammals and is related to various diseases. Molecularly imprinted polymers (MIPs) show unique advantages as phosphorylation recognition reagents, but their performance is currently not ideal. The new approach RMTD-SIC allows for the preparation of monodispersed imprinted nanoparticles for improved phosphorylation recognition.
ANALYTICAL CHEMISTRY
(2021)