期刊
JOURNAL OF CHEMICAL SCIENCES
卷 120, 期 1, 页码 25-31出版社
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-008-0004-5
关键词
polypyrrole; equivalent circuit; impedance spectroscopy; specific capacitance; charge-discharge; supercapacitors
The galvanostatic polymerization of pyrrole is carried out on stainless steel electrodes using p-toluene sulphonic acid. The morphology of the film is studied from Scanning Electron Microscopy (SEM) measurements while the nature of the substrate is analysed using Energy Dispersive X-ray Spectroscopy (EDAX) technique. The electrochemical behaviour is studied using cyclic voltammetry, charge-discharge analysis and impedance spectroscopy. The feasibility of the electrode for supercapacitor applications is investigated. The specific capacitance is estimated as similar to 10(2) Farads per gram with 10(3) charge-discharge cycles. A plausible equivalent circuit for the system is proposed and the circuit parameters are obtained by non-linear regression analysis.
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