Article
Chemistry, Physical
Md Iqbal Hossain, G. J. Blanchard
Summary: Room temperature ionic liquids (RTILs) have unique properties, including the ability to support induced free charge density gradient. When diluted, RTILs form micelle-like structures and show compositional non-uniformity. In this study, we investigated the dilution of two imidazolium RTILs with polar aprotic solvents and found that the properties depend on the RTIL anion. Evidence of aggregated domains in the non-affected regions of RTILs was observed, and the domain size increased with increasing dilution.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Chunhui Li, Hui He, Chenxi Hou, Mingjian He, Caishan Jiao, Qingjiang Pan, Meng Zhang
Summary: The complex behavior of extractants in ionic liquids has been studied through theoretical calculations and simulations, revealing that ion pairs are favored over separated ions and the interaction with the extractant is primarily driven by electrostatic forces. The concentration of the extractant greatly influences the local structures and interactions.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Thermodynamics
Sowjanya Prathipati, Srinivasa Rao Vipparla, Srinivasa Reddy Munnangi, Md Nayeem Sk, Hari Babu Bollikolla
Summary: This study involved the determination of physical parameters and properties of [Bmim][PF6] / N-methylpyrrolidone and their mixtures at various compositions and temperatures. The results indicated strong intermolecular interactions, which increased with temperature. The findings were supported by the Prigogine-Flory-Patterson theory and IR spectra.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2021)
Article
Chemistry, Physical
Kgomotso Masilo, Shailendra Kumar Singh, Indra Bahadur
Summary: This study evaluated the intermolecular interactions between ionic liquids and acetic acid, propionic acid in binary mixtures, discussing the variations of thermodynamic properties with mole fraction and temperature, as well as the impact of IL anion and alkyl length on properties. The experimental results were used to compute thermodynamic properties and were confirmed through FTIR spectra of pure components and binary mixtures at equimolar compositions.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Thermodynamics
Naved Azum, Maroof Ali, Sana Fatima, Abdullah M. Asiri
Summary: This study reveals the synergistic behavior and solute-solvent interactions in the IL-EGME binary mixture through spectroscopic investigations. The results indicate the presence of strong hydrogen bonding between IL and EGME molecules, leading to the formation of a new entity.
FLUID PHASE EQUILIBRIA
(2022)
Article
Chemistry, Multidisciplinary
Md. Ahad Ali, Md. Abu Bin Hasan Susan
Summary: The volumetric properties of ionic liquid, propane-1,2-diol, and their binary mixtures were studied. The results showed that the introduction of the ionic liquid disrupted the intermolecular hydrogen bonds in the propane-1,2-diol system, leading to changes in molecular-level interactions. These interactions play a significant role in determining the thermodynamic properties of the binary mixtures.
Article
Biochemistry & Molecular Biology
Yoshihiro Nishida, Reina Aono, Hirofumi Dohi, Wuxiao Ding, Hirotaka Uzawa
Summary: Glycerol exhibits symmetrical conformations with different ratios of gt, gg, and tg in water, favoring the symmetric conformers with the 1,2,3-triol groups in gauche/gauche geometry. However, the conformational equilibrium of glycerol shifts towards non-symmetric conformers when the solvent is changed to DMSO-d(6) or DMF-d(7).
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
Manjari Chakraborty, Sahadev Barik, Amita Mahapatra, Moloy Sarkar
Summary: The study investigates the impact of lithium ions on the structure and dynamics of ionic liquids, specifically monocationic ILs and dicationic ILs. The addition of lithium ions significantly alters the microscopic behavior of the ILs, especially in the apolar regions. This research provides insights into how lithium ions influence the nanostructural organization of ILs and highlights their potential as electrolytes in battery applications.
JOURNAL OF PHYSICAL CHEMISTRY B
(2021)
Article
Chemistry, Physical
Neha Chaudhary, Anil Kumar Nain
Summary: In this study, the physical properties of 1-butyl-3-methylimidazolium tetrafluoroborate and Benzonitrile binary mixture were measured at different temperatures and atmospheric pressure. Various excess parameters were calculated and the impact of positive or negative deviations on molecular interactions in these mixtures was analyzed. The applicability of the Prigogine-Flory-Patterson theory in predicting values was also assessed.
PHYSICS AND CHEMISTRY OF LIQUIDS
(2021)
