期刊
JOURNAL OF CATALYSIS
卷 299, 期 -, 页码 44-52出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2012.11.028
关键词
Hierarchical zeolites; FeZSM-5; Fenton reaction; Oxidation; Phenol; Lignin
资金
- Department of Science and Education (Federal Target Program Scientific and Educational Personnel)
- Russian Federation President Grant for the Leading Scientific Schools [NSh 524.2012.3]
- BP grant
- [35]
- [24]
Series of hierarchical zeolites ZSM-5 and FeZSM-5 were prepared by hydrothermal treatment using polystyrene spheres template and characterized by X-ray diffraction, UV-vis diffuse reflectance spectroscopy, scanning and high-resolution transmission electron microscopies, and N-2 sorption techniques. Walls of the macroporous structure consisted of ZSM-5 nanocrystals with a size of 20-300 nm and amorphous globules of SiO2. Hierarchical FeZSM-5 contained iron in the form of iron oxide particles with a size of 2-3 nm. Hierarchical zeolites had high values of surface area (437-613 m(2)/g), external surface area (131-462 m(2)/g), and pore volume (0.36-0.76 cm(3)/g). Iron-containing zeolites were tested in the H2O2 decomposition reactions in the absence and presence of iron-complexing agent, as well as in oxidation of low and high molecular weight organic compounds by H2O2 at 25 degrees C and compared with homogeneous Fe(NO3)(3) solution. Hierarchy of the zeolite porosity resulted in a significant improvement of the catalyst properties. (c) 2012 Elsevier Inc. All rights reserved.
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