期刊
JOURNAL OF CATALYSIS
卷 269, 期 2, 页码 376-387出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2009.11.021
关键词
Platinum; Ruthenium; Bimetallic; Dendrimer; Nanoparticle; 3,4-Epoxy-1-butene; Hydrogenation
资金
- National Science Foundation [NSF-0103135]
A series of silica-supported Pt, Ru, and Pt-Ru catalysts has been synthesized using dendrimer-metal nanocomposite (DMN) precursors prepared by both co- and sequential complexation with metal salts. The catalysts have been characterized by several techniques, including electron microscopy, temperature-programmed titration of adsorbed oxygen, and X-ray diffraction. Liquid-phase selective hydrogenation of 3,4-epoxy-1-butene (EpB) was used as a probe reaction to evaluate their catalytic performance. The bimetallic catalyst prepared by the co-complexation method exhibits a superior catalytic activity Compared to the sequential one, and is much more active than a conventional catalyst prepared by incipient wetness. The activity enhancement is attributed to a bifunctional performance of the PtRu alloy sites created, based on a strong correlation between turnover frequencies, and both the alloy compositions and metal Surface site distributions. In addition, the co-complexation catalyst is selective toward crotonaldehyde, suggesting that this reaction pathway is favored on the PtRu sites. (C) 2009 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据