期刊
JOURNAL OF CATALYSIS
卷 255, 期 1, 页码 40-47出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2008.01.022
关键词
polyoxometalate; cobalt; hydrotalcite; pillared; cyclohexanol; oxidation; oxygen
Cobalt-substituted polyoxometalate (POM), alpha-[SiW9O37{Co(H2O)(3)}](10-), was heterogenized for its effective use as a solid catalyst in the liquid-phase reaction by inserting it in between the layers of basic Mg3Al-hydrotalcite. It was characterized by FT-IR, UV-vis, X-ray diffraction, N-2 adsorption-desorption and elemental analysis. A POM cluster was intercalated into the interlayer of layered double hydroxide (LDH), and the integrity of the cluster [SiW9Co3] was maintained when the hydrotalcite precursor, Mg3Al-LDH-carbonate, was transformed into a mixed-oxide solid solution, followed by the formation Of Mg3Al-LDH-hydroxide through hydrolytic reconstruction and Mg3Al-LDH-adipate via anion exchange by organoacid precursor before its use in the pillaring reaction under a stringent N-2 atmosphere. The intercalated cobalt-substituted POM cluster showed high catalytic activity and reusability in the liquid-phase selective oxidation of cyclohexanol to cyclohexanone using 1 atmosphere of molecular oxygen under mild reaction conditions. (c) 2008 Elsevier Inc. All rights reserved.
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